Abstract
The fabrication of high performance materials using liquid phase sintering requires an understanding of the underlying equilibrium phase diagram. Although sintering is not an equilibrium process, it does represent an approach to equilibrium; thus, phase diagrams can aid in defining process variables. The basic concepts are organized to indicate the phase diagram features important to successful sintering in the presence of a liquid phase. Example phase diagrams are offered for liquid metal infiltration of porous metal compacts, persistent liquid phase sintering, supersolidus sintering, transient liquid phase sintering, and reactive sintering.
Similar content being viewed by others
References
R.M. German, Liquid Phase Sintering, (New York, NY: Plenum Press, 1985).
E.R. Lumpkins, “A Theoretical Review of the Copper Infiltration of PM Components,” Powder Met. Inter., 17 (1985), pp. 120–123.
P. Schwarzkopf, “The Mechanism of Infiltration,” Symposium on Powder Metallurgy, Special Report 58, (London, UK: The Iron and Steel Institute, 1956), pp. 55–58.
F.V. Lenel, Powder Metallurgy Principles and Applications, (Princeton, NJ: Metal Powder Industries Federation, 1980), pp. 285–307.
V.N. Eremenko, Y.V. Naidich and I.A. Lavrinenko, Liquid Phase Sintering, (New York, NY: Consultants Bureau, 1970).
C.J. Li and R.M. German, “Enhanced Sintering of Tungsten—Phase Equilibria Effects on Properties,” Inter. J. Powder Met. Powder Tech., 20 (1984), pp. 149–162.
A.P. Savitskii and L.S. Martsunova, “Effect of Solid-State Solubility on the Volume Change Experienced by Aluminum During Liquid Phase Sintering,” Soviet Powder Met. Metal Ceram., 16 (1977), pp. 333–337.
R.M. German and K.A. D’Angelo, “Enhanced Sintering Treatments for Ferrous Powders,” Inter. Metals Rev., 29 (1984), pp. 249–272.
W.J. Huppmann, “The Elementary Mechanisms of Liquid Phase Sintering II. Solution-Reprecipitation,” Z. Metallkde., 70 (1979), pp. 792–797.
W.H. Baek and R.M. German, “Transient Liquid Phase Sintering of Iron-Titanium,” Powder Met. Inter., 17 (1985), pp. 273–279.
J. Puckert, W.A. Kaysser and G. Petzow, “Dimensional Changes During Transient Liquid Phase Sintering of Fe−Ni,” Inter. J. Powder Met. Powder Tech., 20 (1984), pp. 301–310.
S. Yangyun and R.J. Brook, “Preparation of Zirconia-Toughened Ceramics by Reaction Sintering,” Sci. Sintering, 17 (1985), pp. 35–47.
A.P. Savitskii, “Some Characteristic Features of the Sintering of Binary Systems,” Society Powder Met. Metal Ceram., 19 (1980),pp. 488–493.
Y. Miyamoto, M. Koizumi and O. Yamada, “High Pressure Self Combustion Sintering for Ceramics,” J. Amer. Ceramic Soc., 67 (1984), C224–C225.
R.M. German, “The Identification of Enhanced Sintering Systems Through Phase Diagrams,” Modern Developments in Powder Metallurgy, Vol. 15, ed. E.N. Aqua and C.I. Whitman, (Princeton, NJ: Metal Powder Industries Federation, 1985), pp. 253–273.
Additional information
R.M. German received his Ph.D. from the University of California at Davis. He is currently professor in the Materials Engineering Department at Rensselaer Polytechnic Institute.
Rights and permissions
About this article
Cite this article
German, R.M. Phase Diagrams in Liquid Phase Sintering Treatments. JOM 38, 26–29 (1986). https://doi.org/10.1007/BF03257783
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03257783