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Journal of the Iranian Chemical Society

, Volume 3, Issue 3, pp 285–292 | Cite as

Photosensitized oxidation of unsymmetrical 1,4-dihydropyridines

  • H. R. Memarian
  • M. Abdoli-Senejani
  • S. Tangestaninejad
Article

Abstract

Photosensitized oxidation of unsymmetrically substituted 1,4-dihydropyridines using dye sensitizers methylene blue, rose bengal and tetraphenylporphyrin by taking visible light source resulted in the aromatization of dihydropyridine ring and formation of the corresponding pyridine derivatives. Comparison of the results obtained under photosensitized reaction with those obtained by direct photo-oxidation indicated a very fast and smooth reaction of these compounds and formation of pyridine derivatives using theses dyestuffs.

Keyword

1,4-Dihydropyridines Photochemistry Photooxidation Photosensitized oxidation Singlet oxygen 

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Copyright information

© Iranian Chemical Society 2006

Authors and Affiliations

  • H. R. Memarian
    • 1
  • M. Abdoli-Senejani
    • 1
  • S. Tangestaninejad
    • 1
  1. 1.Department of Chemistry, Faculty of ScienceUniversity of IsfahanIsfahanIran

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