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Journal of the Iranian Chemical Society

, Volume 6, Issue 4, pp 769–775 | Cite as

Synthesis, structural elucidation and X-ray analysis of triphenyltin(IV) [2-(2,3-dimethylanilino)nicotinate]

  • M. Hussain
  • M. Zaman
  • M. Hanif
  • M. Altaf
  • S. Ali
  • H. Stoeckli-Evans
Article

Abstract

Triphenyltin(IV) [2-(2,3-dimethylanilino)nicotinate] was prepared by the interaction of triphenyltin(IV) hydroxide and 2-(2,3-dimethylanilino)nicotinic acid in 1:1 ratio. This compound was characterized by elemental analyses, IR, multinuclear NMR spectroscopy (1H and 13C) and mass spectrometry. The structure of title compound was confirmed by single crystal X-ray crystallography. The coordination around the tin atom was studied both in solution and solid state. The geometry around tin is trigonal bipyramidal in solid state while it is tetrahedral in solution. The compound belongs to Monoclinic system, having space group P 21/c with unit cell dimensions a = 17.002(8) Å, b = 9.0793(3) Å, c = 18.2616(9) Å, α = 90 (°) β = 107.381(4) (°), γ = 90 (°).

Keywords

Triphenyltin(IV) derivative NMR X-Ray analysis Pentacoordinated geometry 

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Copyright information

© Iranian Chemical Society 2009

Authors and Affiliations

  • M. Hussain
    • 1
  • M. Zaman
    • 1
  • M. Hanif
    • 1
  • M. Altaf
    • 2
  • S. Ali
    • 1
  • H. Stoeckli-Evans
    • 2
  1. 1.Department of ChemistryQuaid-i-Azam UniversityIslamabadPakistan
  2. 2.Institute of MicrotechnologyUniversity of NeuchátelNeuchátelSwitzerland

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