Journal of the Iranian Chemical Society

, Volume 1, Issue 2, pp 122–127 | Cite as

Study of the kinetics and activation parameters of reduction of Mn(III) to Mn(II) by SO3 2− ion in (MnSiW11O40H2)5- heteropoly ion



In order to gain an insight into the mechanism of reduction of Mn(III) heteropoly ions, and also to establish the conditions for use of some of these ions as oxidizing agent, following measurements have been made. The pseudo-first order rate constants, kobs, have been determined and specific rate constants, k, were calculated from the plots of kobs against SO3 2− concentrations. A plot of ln(k2/T) against inverse temperature gives enthalpy of activation as 10.67 kJ mol−1 and entropy of activation as −237.90 J K−1 mol−1. Effects of ionic strength and pH have also been studied over a limited range.


Heteropoly ion Stopped-flow MPLIX program Rate constant Enthalpy Entropy 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. [1]
    L.C.W. Baker, in: S. Kirschner (Ed.), Advances in Chemistry of the Coordination Compounds, MacMillan, New York, 1961.Google Scholar
  2. [2]
    T.A. Zardan, L.G. Hepler, Chem. Rev. 68 (1968) 737.Google Scholar
  3. [3]
    R.D. Kemmitt, Comprehensive Inorganic Chemistry, Vol. 3, Pergamon, New York, 1973, p. 813.Google Scholar
  4. [4]
    G. Davies, Coord. Chem. Rev. 4 (1969) 199.Google Scholar
  5. [5]
    C.F. Wells, G. Daveis, J. Chem. Soc., A. (1967) 1858.Google Scholar
  6. [6]
    K.A. Kumar, P. Sivaswaroop, K.J. Rao, V.K.P. Rao, Transition Met. Chem. (London) 5 (1987) 441.Google Scholar
  7. [7]
    D.R. Eatan, W.R. Mc Clellan, J.F. Weither, Inorg. Chem. 7 (1968) 2040.Google Scholar
  8. [8]
    S.A. Malik, T.J.R. weakly, J. Chem. Soc. A. (1968) 2467.Google Scholar
  9. [9]
    M.R. Hoffmann, J.O. Edwards, J. Phys. Chem. 79 (1975) 2096.Google Scholar
  10. [10]
    S.A. Malik, T.J.R. Weakly, C.M. Taurne, G.F. Tourne, J. Inorg. Nucl. Chem. 32 (1970) 3875.Google Scholar
  11. [11]
    X.Y. Zhang, C.J. O’Connor, G.B. Jameson, M.T. Pope, Inorg. Chem. 35 (1996) 30.Google Scholar
  12. [12]
    X.Y. Zhang, M.T. Pope, M.R. Chance, G.B. Jameson, Polyhedron 14 (1995) 1381.Google Scholar
  13. [13]
    I.E. Weinstock, R.H. Atalla, R.S. Reiner, M.A. Moen, K.E. Hammel, C.J. Houtman, C.L. Hill, M.K. Harrup, J. Mol. Catal. A: Chem. 116 (1997) 59.Google Scholar
  14. [14]
    I.A. Weinstock, Chem. Rev., 98,1 (1998) 119.Google Scholar
  15. [15]
    W. David, Carlyte, F. Otto Zeek, Inorg. Chem. 12 (1973) 2978.Google Scholar

Copyright information

© Iranian Chemical Society 2004

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of KarachiKarachiPakistan

Personalised recommendations