Abstract
This article provides a brief history of dimensionally stable anodes by reviewing innovations in the chlor-alkali industry, electroplating and electrogalvanizing, and electrowinning. These anodes are attractive for numerous reasons (e.g.,.long life and reduced energy consumption), but they must still overcome the hurdle of cost togain wider acceptance for applications in the metallurgical process industries.
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A.T. Kuhn and P.M. Wright, “Electrodes for Industrial Processes,” Industrial Electrochemical Processes, ed. A.T. Kuhn (Amsterdam, the Netherlands: Elsevier, 1971), pp. 545–561.
R. Baboian, “Clad Metal Anodes,” Chlorine Bicentennial Symposium (San Francisco, CA: May 1974), pp. 158–173.
H.B. Beer, Belgian patent 710,751 (1968); British patent 1,147,442 (1969); U.S. patent 3,632,498 (1972); U.S. patent 3,711,385 (1973).
H.B. Beer, “The Invention and Industrial Development of Metal Anodes,” J. Electrochem. Soc., 127 (1980), pp. 303C–307C.
H.S. Holden and J.M. Kolb, “Metal Anodes,” Encyclopedia of Chemical Technology, vol. 15 (New York: John Wiley & Sons, 1981), pp. 172–183.
K.J. O’Leary and T.J. Navin, “Morphology of Dimensionally Stable Anodes,” Chlorine Bicentennial Symposium (San Francisco, CA: May 1974), p. 174.
S. Trasati and W.E. O’Grady, “Properties and Applications of Ruthenium Oxide Based Electrodes,” Advances in Electrochemistry and Electrochemical Engineering, ed. H. Gerisher and C.W. Tobias, vol. 12 (New York: John Wiley & Sons, 1981), pp. 177–261.
S. Trasatti, ed., Electrodes of Conductive Metal Oxides, Parts A and B (Amsterdam, the Netherlands: Elsevier, 1980 and 1981).
C.E. Vallet et al. “DSA RuO2/TiO2 Electrode Modeled by Ion Implantation: An In-Situ Characterization by Photo-acoustic and Photocurrent Spectroscopy,” J. Electrochem. Soc., 135 (1988), pp. 387–395.
B.V. Tilak, K. Taxi, and C.L. Hoover, “Metal Anodes and Hydrogen Cathodes: Their Activity Towards Oxygen Evolution and Chlorate Reduction Reactions,” J. Electrochem. Soc., 135 (1988), pp. 1386–1392.
M. Yoshida and Y. Noaki, “Recent Developments in Anodes and Cathodes for Chlor-Alkali Electrolysis,” Performance of Electrodes for Industrial Processes, ed. F. Hine et al. (Princeton, NJ: the Electrochemical Society, 1989).
T. Shimamune et al. “Anode Characteristics in Chlor-Alkali Membrane Electrolysis,” in Ref. 11.
T. Shimamune et al., “Behavior of DSA Coating in Chlor-Alkali Membrane Electrolyser,” in Ref. 11.
T. Muranaga, Y. Kanaya, and N. Yokata, “Characteristics of Platinum Group Metal Anodes for Chlor-Alkali Cells,” in Ref. 11.
K. Hitrakata et al., “Development of Anodes for On-Site Hypochlorite Generation,” in Ref. 11.
N. Munichandraiah and S. Sathyanarayana, “Insoluble Anode of α-Lead Dioxide Coated on Titanium for Electrosynthesis of Sodium Perchlorate,” J. Appl. Electrochem., 18 (1988), pp. 314–316.
L.D. Burke and M.M. McCarthy, “Modification of the Electronic Transfer Properties of CO3O4 as Required for its Use in DSA-Type Anodes,” J. Electrochem. Soc., 135 (1988), pp. 1175–1179.
R.M. Skomoroski et al., “Performance of Platinum-Clad Anodes in Electroplating,” Plating (November 1973).
S. Kotowski and B. Busse, “Titanium Anodes for Steel Strip Electrogalvanizing,” in Ref. 11.
W.N. Brooks, D.A. Denton, and N.M. Sammes, “ICI Electrodes Coatings—From Mercury Cells to Automobile Bodies,” in Ref. Ref. 11, pp. 39–55.
J.M. McIntyre, “Anode Corrosion During Cathodic Electrodeposition of Organic Coatings,” in Ref. 11.
F. Hine, K. Takayasu, and N. Koyanagi, “A Platinized Titanium Anode for Chromium Electroplating,” J. Electrochem, Soc., 133 (1986), pp. 346–350.
K.L. Hardee, L.K. Mitchell, and E.J. Rudd, “Catalytic Anodes for High-Speed Electroplating and Electrogalvanizing,” Plating and Surface Finishing, 76 (4) (1989), pp. 68–71.
M. Fujimori et al., “Electrowinning from Aqueous Chlorides in SMM’s Nickel and Cobalt Refining Process,” Chloride Electrometallurgy, ed. P.D. Parker (Warrendale, PA: TMS, 1982), pp. 155–166.
E.O. Stensholt, H. Zachariasen, and J.H. Lund, “Falconbridge Chlorine Leach Process,” Trans. Instn. Mng. Metall. (C), 95 (1986), pp. C10–C16.
G. Lodi et al., “Ruthenium Dioxide-Based Film Electrodes—Effect of Chemical Composition and Surface Morphology on Oxygen Evolution in Acid Solutions,” J. Appl. Electrochem., 8 (1978), pp. 135–143.
R. Baboian, “Clad Metal Anode for Electrowinning” (Paper presented at the 78th National Meeting of the AIChE, Salt Lake City, UT, 1974).
D. Wensley and I.H. Warren, “Progressive Degradation of Noble Metal Coated Titanium Anodes in Sulfuric Acid and Acidic Copper Sulfate Electrolytes,” Hydrometallurgy, 1 (1976), pp. 259–276.
D. Wensley and I.H. Warren, “Corrosion and Passivation Behavior of Noble Metal Coated Anodes in Copper Electrowinning Applications,” Metall. Trans. B., 10B (1979), pp. 503–511.
A.J. Scarpellino, Jr., and G.L. Fisher, “The Development of an Energy-Efficient Insoluble Anode for Nickel Electrowinning I. Single Layer Precious Metal Coatings,” J. Electrochem. Soc., 129 (1982), pp. 515–521.
A.J. Scarpellino, Jr., and G.L. Fisher, “The Development of an Energy-Efficient Insoluble Anode for Nickel Electrowinning II. Multilayer Precious Metal Coatings,” J. Electrochem. Soc., 129 (1982), pp. 522–528.
C.J. Ferron, “Investigation of the Behavior of Precious Metal Coated Anodes in Copper Electrowinning,” Ph.D. thesis, Columbia University (1988).
C.J. Ferron and P.F. Duby, “Iridium Oxide Coated Titanium Anode in Copper Electrowinning,” Performance of Electrodes for Industrial Electrochemical Processes, ed. F. Hine et al. (Princeton, NJ: the Electrochemical Society, 1989), pp. 259–277.
C.J. Ferron and P.F. Duby, “Stability of an Iridium Oxide Coated Titanium Anode in Copper Electrowinning,” EPD Congress 1992, ed. J.P. Hager (Warrendale, PA: TMS, 1992), pp. 137–153.
J. Rolewicz et al., “Characterization of DSA-Type Oxygen Evolving Electrodes,” Electrochem. Acta, 33 (1988), pp. 573–580.
Ch. Comminellis, “Characterization of DSA-Type Oxygen Evolving Anodes,” in Ref. 11.
H.B. Beer, “Progress in Anodes for Metal Winning,” Extended Abstracts 83-1 (Princeton, NJ: the Electrochemical Society, 1983), p. 874.
J.K. Walker and J.I. Bishara, “Electrocatalytic Anode for Copper Electrowinning,” Anodes for Electrowinning, D.J. Robinson and S.E. James (Warrendale, PA: TMS, 1984), pp. 79–86.
K.R. Koziol and E.F. Wenk, “The Advantages of Coated Titanium Electrodes for Electrowinning Processes of Different Metals,” in Ref. 38, pp. 87–100.
G. Bewer et al., “Sintered Titanium Anodes in Metals Electrowinning,” in Ref. 38, pp. 101–112.
G. Bewer, H. Debrodt, and H. Herbst, “Titanium for Electrochemical Processes,” J. Metals, 34 (1) (1982), pp. 37–41.
Y. Liu, L. Wu, and B. Yuan, “Energy Saving DSA for Nickel and Zinc Electrowinning—A Laboratory Study,” Nonferrous Met. (China), 37 (3) (August 1985), pp. 53–58 (in English).
I. Enchev, G. Georgiev, and Ts. Uzunov, “Electrochemical Study of a New Type of Anode for Electrolytic Extraction of Zinc,” Metallurgiya (Sofia), 41 (1) (1986), pp. 6–8 (in Bulgarian); Metals Abstracts (1986), p. 42–1126.
D.L. Piron, “Recent Improvements in Zinc Alkaline Hydrometallurgy,” Electrometallurgical Plant Practice, ed. P.L. Claessens and G.B. Harris (New York: Pergamon Press, 1990), pp. 129–140.
P. Ardelean at al., “High Intensity Zinc Electrowinning at the Laboratory and Small Technical Scale,” Electrometallurgical Plant Practice, ed. P.L. Claessens and G.B. Harris (New York: Pergamon Press, 1990), pp. 115–127.
V.A. Ettel, “Energy Requirements in Electrolytic Winning and Refining of Metals,” CIM Bulletin (July 1977), pp. 179–187.
B.V. Tilak and S. Venkatesh, “Anodes in Electrochemical Operations: State of the Art, Problems Areas, and Future D&D Needs,” Electrochemistry Research Needs for Mineral and Primary Materials Processing, ed. T.J. O’Keefe and J.W. Evans (Washington, D.C.: U.S. Bureau of Mines and National Science Foundation, 1983), pp. 195–207.
I.H. Warren, “The Oxygen Electrode in Metal Electrowinning,” Anodes for Electrowinning, in Ref. 38, pp. 69–78.
J.A. Wells and W.R. Snelgrove, “The Design and Engineering of Copper Electrowinning Tankhouses,” Electrometallurgical Plant Practice, ed. P.L. Claessens and G.B. Harris (New York: Pergamon Press, 1990), pp. 57–72.
J.G. Jenkins and M.A. Eamon, “Plant Practice and Innovations at Magma Copper Company’s San Manuel SX-EW Plant,” Electrometallurgical Plant Practice, ed. P.L. Claessens and G.B. Harris (New York: Pergamon Press, 1990), pp. 41–57.
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Duby, P. The history of progress in dimensionally stable anodes. JOM 45, 41–43 (1993). https://doi.org/10.1007/BF03222350
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DOI: https://doi.org/10.1007/BF03222350