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Macromolecular Research

, Volume 12, Issue 6, pp 604–607 | Cite as

Synthesis and characterization of ω-sulfonated polystyrene-stabilized cadmium sulfide nanoclusters

  • Yong Hyun Jin
  • Jungahn Kim
  • Seung Soon Im
Article
  • 56 Downloads

Abstract

We report an important and useful method for preparing ω-sulfonated polystyrene-stabilized cadmium sulfide (CdS) nanoclusters. The ω-sulfonated polystyrene (M n = 5000 g/mol) was prepared successfully through chain-end sulfonation of poly(styryl)lithium using 1,3-propanesultone; the resulting polymer was used successfully as a polymeric stabilizing agent for the preparation of semiconductor CdS nanoclusters by reduction of cadmium acetate in a mixture of toluene and methanol (9∶1, v/v). The nanoclusters that formed were characterized by a combination of transmission electron microscopy, X-ray diffraction, and UV/Vis spectroscopic analysis. The ω-sulfonated polystyrene-stabilized CdS nanoclusters synthesized in this study exhibited the cubic phase (zinc-blende phase) structure in the range of 2∼8 nm.

Keywords

cadmium sulfide chain-end sulfonation nanoclusters semiconductor ω-sulfonated polystyrene 

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Copyright information

© The Polymer Society of Korea and Springer 2004

Authors and Affiliations

  • Yong Hyun Jin
    • 1
  • Jungahn Kim
    • 1
  • Seung Soon Im
    • 2
  1. 1.Polymer Hybrids CenterKorea Institute of Science and TechnologySeoulKorea
  2. 2.Department of Textile EngineeringHanyang UniversitySeoulKorea

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