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Significance of inclusions in electroplated gold films for electronics applications

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Abstract

Minute amounts of metallic as well as non-metallic inclusions significantly affect both bulk and surface properties of the electroplated gold films being used by the electronics industry. Surface effects are caused by the presence of extraneous materials diffused out from the interior to the surface, while bulk effects are brought about by the influence of inclusions on the microstructure of the gold films. This article reviews the current status of understanding of such inclusion effects in both soft and hard gold: these play essential roles in the fabrication of today's microelectronic devices.

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References

  1. W.H. Safranek, ‘The Properties of Electrodeposited Metals and Alloys’, Second Edition, American Electroplaters and Surface Finishers Society, Orlando, Florida, 1986

    Google Scholar 

  2. H.A. Reinheimer,J. Electrochem. Soc., 1974,121, 490

    Article  CAS  Google Scholar 

  3. T. Osaka, A. Kodera, T. Misato, T. Homma, Y. Okinaka and O. Yoshioka,J. Electrochem. Soc., 1997,144, 3462

    Article  CAS  Google Scholar 

  4. ‘Gold Plating Technology”, ed. F.H. Reid and W. Goldie, Electrochemical Publications, Ltd., Ayr, Scotland, 1974

    Google Scholar 

  5. W.S. Rapson and T. Groenewald, ‘Gold Usage’, Academic Press, London, 1978

    Google Scholar 

  6. F.B. Koch, Y. Okinaka, C. Wolowodiuk and D.R. Blessington,Plating, 1980,67(6), 50; 1980,67(7), 43

    CAS  Google Scholar 

  7. Y. Okinaka and F.B. Koch, ‘Proceedings of the 10th World Congress on Metal Finishing (Interfinish 80)’, 1980, pp.48–52

  8. D.M. MacArthur,J. Electrochem. Soc., 1972,119, 672

    Article  CAS  Google Scholar 

  9. J.D.E. McIntyre and W.F. Peck, Jr.,J. Electrochem. Soc., 1976,123, 1800

    Article  CAS  Google Scholar 

  10. E.T. Eisenmann,J. Electrochem. Soc., 1978,125, 717

    Article  CAS  Google Scholar 

  11. S. Nakahara and Y. Okinaka,J. Electrochem. Soc., 1981,128, 284

    Article  CAS  Google Scholar 

  12. G. Holmbom and B.E. Jacobson,J. Electrochem. Soc., 1988,135, 787

    Article  CAS  Google Scholar 

  13. T. Sawaguchi, T. Yamada, Y. Okinaka and K. Itaya,J. Phys. Chem., 1995,99, 14149

    Article  CAS  Google Scholar 

  14. R. Duva and A. Simonian,US Patent 3, 562,120,1971

    Google Scholar 

  15. H.A. Reinheimer,US Patent 3,833,487, 1974

    Google Scholar 

  16. L. Greenspan,US Patent 3,423,295, 1969

    Google Scholar 

  17. R. Zimmerman and R. Brenneman,British Patent 1,275,386, 1972

    Google Scholar 

  18. S.T. Rao and R. Weil,Metal Finishing, 1979,57, 97

    CAS  Google Scholar 

  19. T.E. Dinon and H.Y. Cheh,J. Electrochem. Soc., 1992,139, 410

    Article  Google Scholar 

  20. D.W. Endicott, H.K. James and F. Nobel,Plating and Surface Finish.,1981,68(11), 58

    CAS  Google Scholar 

  21. S. Wakabayashi, A. Murata and N. Wakabayashi,Plating and Surface Finish., 1982,69(8), 63

    CAS  Google Scholar 

  22. S. Wakabayashi, K. Harayama, S. Iwai and M. Nakazawa,Kinzoku Hyomen Gijutsu (J. Metal Finish. Soc. Japan), 1988,39, 189

    CAS  Google Scholar 

  23. A. Chinda and O. Yoshioka,Kinzoku Hyomen Gijutsu (J. Metal Finish. Soc. Japan), 1988,39, 210

    CAS  Google Scholar 

  24. Y. Okinaka, ‘Proceedings of the Symposium on Electrodeposition Technology — Theory and Practice’, ed. L.T. Romankiw and D.R. Turner, The Electrochemical Society, Inc., 1987,87–17, 147

  25. Y. Okinaka, in ‘Precious Metals — Modern Technologies and Applications (EAST Report 1991)’, European Academy of Surface Technology, Schwäbisch Gmünd, Germany, 1991, pp. 8–18

    Google Scholar 

  26. P.A. Kohl, in ‘Modern Electroplating, Fourth Edition’, ed. M. Schlesinger and M. Paunovic, John Wiley and Sons, Inc., 2000, pp. 201–225

  27. J. Ushio, O. Miyazawa, H. Yokono and A. Tomizawa,US Patent 4, 804, 559, 1989

    Google Scholar 

  28. T. Inoue, S. Ando, H. Okudaira, J. Ushio, A. Tomizawa, H. Takehara, T. Shimazaki, H. Yamamoto and H. Yokono, ‘Proceedings of the 45th IEEE Electronic Components Technology Conference’, 1995, p.1059

  29. M. Kato, K. Niikura, S. Hoshino and I. Ohno,Hyomen Gijutsu (J. Surface Finish. Soc. Japan), 1991,42, 729

    CAS  Google Scholar 

  30. M. Kato, Y. Yazawa and Y. Okinaka, ‘Proceedings of AESF Technical Conference, SUR/FIN 95’, American Electroplaters and Surface Finishers Society, 1995, pp. 805–813

  31. K. Yoshizawa, J. Sato, M. Kato, T. Misato, T. Homma, Y. Okinaka, O. Yoshioka and T. Osaka, Extended Abstract of the Paper Presented at the 101st Technical Conference of the Surface Finishing Society of Japan, 2000, Paper 23D-10

  32. X. Wang, N. Issaev and J.G. Osteryoung,J. Electrochem. Soc., 1998,145, 974

    Article  CAS  Google Scholar 

  33. S. Nakahara, Lucent Technologies, Private communication, 1999

  34. C.C. Lo, J.A. Augis and M.R. Pinnel,J. Appl. Phys., 1979,50, 6887

    Article  CAS  Google Scholar 

  35. Y. Okinaka and S. Nakahara,J. Electrochem. Soc., 1976,123, 1284

    Article  CAS  Google Scholar 

  36. G.B. Munier,Plating, 1969,56, 1159

    Google Scholar 

  37. Ch.J. Raub, A. Knödler and J. Lendvey,Plating, 1976,63, 35

    CAS  Google Scholar 

  38. Y. Okinaka, F.B. Koch, C. Wolowodiuk and D.R. Blessington,J. Electrochem. Soc., 1978,125, 1745

    Article  CAS  Google Scholar 

  39. B.M. Chadwick and A.G. Sharpe, in ‘Advances in Inorganic Chemistry and Radiochemistry’, Vol 8, 1966, pp.83–176

  40. D. Kahn, ‘Proceedings of AESF Technical Conference, SUR/FIN 92’, 1992, p.305

  41. S. Nakahara and Y. Okinaka, in ‘Properties of Electrodeposits — Their Measurements and Significance’, ed. R. Sard, H. Leidheiser, and F. Ogburn, The Electrochemical Society, Inc., 1975, pp.50–62

  42. W. Fluehmann, F.H. Reid, R.A. Mausli and S.G. Steinemann,Plating and Surface Finish., 1980,67(6), 62

    CAS  Google Scholar 

  43. S. Nakahara,J. Electrochem. Soc., 1989,136, 451

    Article  CAS  Google Scholar 

  44. P.K. Gallagher,Thermochim. Acta, 1980,41, 323

    Article  CAS  Google Scholar 

  45. Ch.J. Raub,Plating and Surface Finish., 1993,80(9), 30

    CAS  Google Scholar 

  46. B. Bozzini, G. Giovanelli, S. Natali, B. Brevaglieri, P.L. Cavallotti and G. Signorelli,Engineering Failure Analysis, 1998,6, 83

    Article  Google Scholar 

  47. P.L. Cavallotti, Private Communication, 1999.

  48. Y. Okinaka and T. Homma, ‘Proceedings of the Third International Symposium on Electrochemical Technology Applications in Electronics’, ed. L.T. Romankiw, T. Osaka, Y. Yamazaki and C. Madore, The Electrochemical Society, Inc., 1999,99–34, 132

  49. J.E. Graebner and Y. Okinaka,J. Appl. Phys., 1986,60(1), 36

    Article  CAS  Google Scholar 

  50. Ch.J. Raub, Private Communication, 1992

  51. Y. Okinaka and M. Hoshino,Gold Bull., 1998,31(1), 3

    CAS  Google Scholar 

  52. J.H. Thomas and S.P. Sharma,J. Electrochem. Soc., 1979,126, 445

    Article  CAS  Google Scholar 

  53. R. DeDonker and J. Vanhumbeeck,Trans. Inst. Met. Finish., 1985,62(2), 59

    Google Scholar 

  54. M. Huck,Metallwiss. u. Technik, 1992,46, 132

    Google Scholar 

  55. M. Antler,Plating and Surface Finish., 1998,85(12), 85

    CAS  Google Scholar 

  56. M. Antler, Private Communication, 1989

  57. M. Antler,IEEE Transactions on Components, Hybrids, and Manufacturing Technology,CHMT-4, No.1, 15 (1981)

    Article  Google Scholar 

  58. J.P. Celis, J.R. Roos, W. Van Vooren and J. Vanhumbeeck,Trans. Inst. Met. Finish., 1989,67, 70

    Google Scholar 

  59. J.A. Abys, G.F. Breck, H.K. Straschil, I. Boguslavsky and G. Holmbom,Plating and Surface Finish., 1999,86(1), 108

    CAS  Google Scholar 

  60. A. Kobayashi, S. Takano and T. Kubono,Technical Reports of IEICE, 1995,EMD 95-57

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Okinaka, Y. Significance of inclusions in electroplated gold films for electronics applications. Gold Bull 33, 117–127 (2000). https://doi.org/10.1007/BF03215489

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  • DOI: https://doi.org/10.1007/BF03215489

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