Advertisement

Gold Bulletin

, Volume 40, Issue 1, pp 31–35 | Cite as

Gold catalysis: News from the homogeneous wing

  • A. Stephen
  • K. Hashmi
  • Filiz Ata
  • Jan W. Bats
  • M. Carmen Blanco
  • Wolfgang Frey
  • Melissa Hamzic
  • Matthias Rudolph
  • Ralph Salathé
  • Sascha Schäfer
  • Michael Wölfle
Open Access
Gold 2006 Presentation

Abstract

Phenol synthesis using a homogeneous gold catalyst serves as an example of the tremendous progress in homogeneous catalysis by gold which has been made in the past few years. Various aspects of this reaction, including catalyst selectivity and activity and the simple conditions used are described; and the mechanism is discussed in this context.

Keywords

Gold Catalyst Homogeneous Catalysis CARBOXYLATO Single Crystal Structure Analysis Transition Metal CATALYSED 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    G. Dyker, Angew. Chem., 2000,112, 4407;Angew Chem. Int. Ed., 2000,39, 4237CrossRefGoogle Scholar
  2. 2.
    A.S.K. Hashmi,Gold Bull., 2003,36, 3CrossRefGoogle Scholar
  3. 3.
    A.S.K. Hashmi,Gold Bull., 2004,37, 51Google Scholar
  4. 4.
    A. Arcadi and S. Di Giuseppe,Curr. Org. Chem., 2004,8, 795CrossRefGoogle Scholar
  5. 5.
    A. Hoffmann-Röder and N. Krause,Org. Biomol. Chem., 2005,3, 387CrossRefGoogle Scholar
  6. 6.
    A.S.K. Hashmi,Angew. Chem., 2005,117, 7150;Angew. Chem. Int. Ed., 2005,44, 6990CrossRefGoogle Scholar
  7. 7.
    A.S.K. Hashmi and G.J. Hutchings,Angew. Chem., 2006,118, 8064;Angew. Chem. Int. Ed., 2006,45, 7896CrossRefGoogle Scholar
  8. 8.
    A.S.K. Hashmi, T. M. Frost and J. W. Bats,J. Am. Chem. Soc., 2000,122, 11553CrossRefGoogle Scholar
  9. 9.
    A.S.K. Hashmi, T.M. Frost and J.W. Bats,Org. Lett., 2001,3, 3769CrossRefGoogle Scholar
  10. 10.
    A.S.K. Hashmi, J.P. Weyrauch, M. Rudolph and E. Kurpejovic,Angew. Chem., 2004,116, 6707;Angew. Chem. Int. Ed., 2004,43, 6545CrossRefGoogle Scholar
  11. 11.
    S. Carrettin, M.C. Blanco, A. Corma and A.S.K. Hashmi,Adv. Synth. Catal., 2006,348, 1283CrossRefGoogle Scholar
  12. 12.
    B. Martín-Matute, D.J. Cardenas and A.M. Echavarren,Angew. Chem., 2001,113, 4890;Angew. Chem. Int. Ed., 2001,40, 4754CrossRefGoogle Scholar
  13. 13.
    A.S.K. Hashmi, M. Wölfle, F. Ata, M. Hamzic, R. Sálate and W. Frey,Adv. Synth. Catal., 2006,348, 2501CrossRefGoogle Scholar
  14. 14.
    A.S.K. Hashmi, T.M. Frost and J.W. Bats,Catal. Today, 2002,72, 19CrossRefGoogle Scholar
  15. 15.
    A.S.K. Hashmi, M. Rudolph, J.P. Weyrauch, M. Wölfle, W. Frey, and J.W. Bats,Angew. Chem., 2005,117, 2858;Angew. Chem. Int. Ed., 2005,44, 2798CrossRefGoogle Scholar
  16. 16.
    A.S.K. Hashmi, L. Ding, P. Fischer, J.W. Bats and W. Frey,Chem. Eur. J., 2003,9, 4339CrossRefGoogle Scholar
  17. 17.
    A.S.K. Hashmi and L. Grundl,Tetrahedron, 2005,61, 6231–6236CrossRefGoogle Scholar
  18. 18.
    A.S.K. Hashmi, P. Haufe, C. Schmid, A. Rivas Nass and W. Frey,Chem. Eur. J., 2006,12, 5376CrossRefGoogle Scholar
  19. 19.
    A.S.K. Hashmi, J.P. Weyrauch, E. Kurpejovic, T.M. Frost, B. Miehlich, W. Frey and J.W. Bats,Chem. Eur. J., 2006,12, 5806CrossRefGoogle Scholar
  20. 20.
    R. Uson, A. Laguna and M.V. Castrillo,Synth. React. Inorg. Met.-Org. Chem., 1979,9, 317CrossRefGoogle Scholar
  21. 21.
    A. Bayler, A. Bauer and H. Schmidbaur,Chem. Ber./Recueil, 1997,130, 115CrossRefGoogle Scholar
  22. 22.
    A.S.K. Hashmi, M.C. Blanco, E. Kurpejovic, W. Frey and J.W. Bats,Adv. Synth. Catal., 2006,348, 709CrossRefGoogle Scholar
  23. 23.
    A.S.K. Hashmi, R. Salathé and W. Frey,Chem. Eur. J., 2006,12, 6991CrossRefGoogle Scholar

Copyright information

© World Gold Council 2007

Authors and Affiliations

  • A. Stephen
    • 1
  • K. Hashmi
    • 1
  • Filiz Ata
    • 1
  • Jan W. Bats
    • 1
  • M. Carmen Blanco
    • 1
  • Wolfgang Frey
    • 1
  • Melissa Hamzic
    • 1
  • Matthias Rudolph
    • 1
  • Ralph Salathé
    • 1
  • Sascha Schäfer
    • 1
  • Michael Wölfle
    • 1
  1. 1.Institut für Organische ChemieUniversität StuttgartStuttgartGermany

Personalised recommendations