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Gold Bulletin

, Volume 7, Issue 2, pp 39–40 | Cite as

Compounds with gold-antimony bonds

Their potential activity in homogeneous catalysis
  • Maurice C. Muller
Open Access
Article

Abstract

A new field of interest in the chemistry of gold has been opened up by the preparation and characterisation of complexes containing gold-to-antimony metal-metal bonds. These exhibit catalytic properties similar to those of the well known platinum-tin complexes, and may also have potential value in the homogeneous hydrogenation of olefins.

Keywords

SnCl3 AuCl Ferrocenyl PtCl2 Stannous Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    J. F. Young, Adv. Inorg. Chem. Radiochem., 1968, 11, 92; E. H. Brooks and R. J. Cross, Organometal. Chem. Rev. (A), 1970, 6, 227Google Scholar
  2. 2.
    R. Ugo, Aspects of Homogeneous Catalysis, C. Manfredi ed., Milan, 1970. See pp. 15–24 and the references therein; G. N. Schrauzer, Transition Metals in Homogeneous Catalysis, Marcel Dekker, 1971Google Scholar
  3. 3.
    J. F. Young, R. D. Gillard and G. Wilkinson, J. Chem. Soc, 1964, 5176; R. V. Lindsey, G. W. Parshall and U. G. Stolberg, J. Am. Chem. Soc, 1965, 87, 658; G. W. Parshall, J. Am. Chem. Soc, 1966, 88, 704Google Scholar
  4. 4.
    H. A. Tayim and J. C. Bailar, J. Am. Chem. Soc, 1967, 89, 4330CrossRefGoogle Scholar
  5. 5.
    R. Cramer and R. V. Lindsey, J. Am. Chem. Soc, 1966, 88, 3534CrossRefGoogle Scholar
  6. 6.
    J. A. Dilts and M. P. Johnson, Inorg. Chem., 1966, 5, 2079; F. Glocking and M. D. Wilbey, J. Chem. Soc. (A), 1968, 2168CrossRefGoogle Scholar
  7. 7.
    L. Malatesta, L. Naldini, G. Simonetta, and F. Cariati, Coord. Chem. Rev., 1966, 1, 255CrossRefGoogle Scholar
  8. 8.
    W. R. Cullen, D. J. Patmore and J. R. Sams, Inorg. Chem., 1973, 12, 867 and references thereinCrossRefGoogle Scholar
  9. 9.
    M. C. Muller, R. J. H. Clark and R. S. Nyholm, submitted for publicationGoogle Scholar
  10. 10.
    W. Beck, K. H. Stetter, S. Tadros, and K. E. Schwarzhans, Chem. Ber., 1967, 100, 3944; W. Beck and S. Tadros, Zeit. Anorg. Allgem. Chem., 1970, 375, 231; R. S. Nyholm, J. F. Skinner and M. H. B. Stiddard, J. Chem. Soc. (A), 1968, 38; B. R. Hollebone and R. S. Nyholm, J. Chem. Soc (A), 1971, 332; M. E. Peach, Canad. J. Chem., 1968, 46, 2699CrossRefGoogle Scholar

Copyright information

© World Gold Council 1974

Authors and Affiliations

  • Maurice C. Muller
    • 1
  1. 1.Institut de ChimieUniversité Louis PasteurStrasbourg

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