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Gold Bulletin

, Volume 42, Issue 4, pp 302–309 | Cite as

Group 11 complexes with the 1,1′Bis[N,N′-(2-(diphenylphosphino) amide] ferrocene ligand

  • Javier E. Aguado
  • M. Concepción Gimeno
  • Antonio Laguna
  • M. Dolores Villacampa
Open Access
Article

Abstract

The ligand 1,1-bis[N,N′-(2-diphenylphosphino) amide]ferrocene, Fc(CONHCH2CH2PPh2)2 (L), has been synthesized by reaction of the chloro carbonyl derivative Fc(COCl)2 and the aminophosphine NH2CH2CH2PPh2. The coordination properties towards silver(I), gold(I) and gold(III) compounds have been explored. Several complexes with the diphosphine acting as bidentate chelating or bridgind ligand have been prepared. Furthermore the dinuclear species [Au2Fc(CONCH2CH2PPh2)2] with the ligand coordinated through the phosphorus and the deprotonated amido group have been achieved.

Keywords

Ferrocene Diphenylphosphino Diphosphine Coordination Property Aminophosphine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© World Gold Council 2009

Authors and Affiliations

  • Javier E. Aguado
    • 1
  • M. Concepción Gimeno
    • 1
  • Antonio Laguna
    • 1
  • M. Dolores Villacampa
    • 1
  1. 1.Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de AragónUniversidad de Zaragoza-C.S.I.C.ZaragozaSpain

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