Skip to main content
SpringerLink
Log in

Synthesis, crystal structure and thermal behavior of Rb(NTO) · H2O

  • Reviews
  • Published:
Chinese Science Bulletin

Abstract

The Rb(NTO) · H2O crystal has been synthesized by reaction of 3-nitro-1,2,4-triazole-5-one (NTO) with Rb2CO3 in aqueous solution. Its crystal structure has been determined. The crystal belongs to monoclinic system. Crystal structure data: space group P211n; a=0.633 0(1),b = 0.824 1(2),c =1.296 4(3) nm; β =97.90(1)°;V= 0.669 9 (2) nm3,Z = 4,D c = 2.306 g/cm3, μ = 7.365 nm−1, F(000) = 448. An eight coordinated compound is formed between Rb+ with oxygen atoms and nitrogen atoms. A layer structure is formed by coordination bonds and hydrogen bonds. The thermal decomposition mechanism of this coordination compound is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rethgery, E. F., Audette, R. C., Wedlich, D. C., The study of the thermal decomposition of 3-nitro-1,2,4-triazol-5-one (NTO) by DSC, TG-AMS and ARC, Thermochim. Acta, 1991(2): 235.

  2. Spear, R. J., Louey, C. N., Wolfson, M. G. et al., A Preliminary Assessment of 3-Nitro-1,2,4-Triazol-5-one (NTO) as an Insensitive High Explosive, MRL-Tb-89-18, Maribyrnong, Vic: Materials Research Laboratory, 1989.

    Google Scholar 

  3. Li Jiarong, Chen Boren, Crystal structure of ammonium 3-nitro-1,2,4-triazol-5-onate, Propellants Explosives Pyrotechnics, 1991, 16: 145.

    Article  Google Scholar 

  4. Song Jirong, Hu Rongzu, Li Fuping et al., Preparation, molecular structure and thermodynamical properties of [Sr(NTO)2− (H2O)4]2 · 2H2O, Acta Chimica Simca (in Chinese), 2000, 58(2): 222.

    Google Scholar 

  5. Zhang Tonglai, Hu Rongzu, Li Fuping et al., Preparation, crystal structure and thermal decomposition mechanism of [Cu(NTO)2(H2O)] · 2H2O, Chinese Science Bulletin (in Chinese), 1993, 38(6): 523.

    Google Scholar 

  6. Song Jirong, Chen Zhaoxu, Xiao Heming et al., Preparation, crystal structure and quantum chemical investigation of [Li(NTO)(H2O)], Chinese Science Bulletin 1999, 44(3): 214.

    Article  Google Scholar 

  7. Hu Rongzu, Song Jirong, Li Fuping, Preparation, crystal structure, the decomposition mechanism and thermodynamical properties of (Dy(NTO)2 · (H2O)6] · NTO · H2O, Thermochim. Acta, 1997, 299: 87.

    Article  Google Scholar 

  8. Geilonann, W., Gebauhr, W., Zur Fallung der alkalimetalle als tetraphenylborverbindungen, Z. Anal. Chem., 1953, 139: 161.

    Article  Google Scholar 

  9. Song Jirong, Study on Metal Coordination Compounds of NTO (in Chinese), Beijing: Chemical Industry Publishing Company, 1998, 1–3.

    Google Scholar 

  10. Prabbakaran, K. V., Naidu, S. R., XRD spectroscope and thermal analysis studies on NTO, Thermochim. Acta, 1994, 241: 199.

    Article  Google Scholar 

  11. Song Jirong, Chen Zhaoxu, Xiao Heming et al., Preparation, crystal structure and quantum chemical investigation of [Yb(NTO)3 (H2O)4], Acta Chimica Simca (in Chinese), 1998, 56 (3): 270.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Applied Chemistry, Shaanxi Normal University, 710062, Xi’an, China

    Mancheng Hu, Shiyang Gao, Zhihong Liu & Shuping Xia

  2. Department of Chemical Engineering, Northwest University, 710069, Xi’an, China

    Jirong Song

  3. Chengdu Branch of Chinese Academy of Sciences, 610041, Chengdu, China

    Kaibei Yu

Authors
  1. Mancheng Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shiyang Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhihong Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jirong Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shuping Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Kaibei Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shiyang Gao.

About this article

Cite this article

Hu, M., Gao, S., Liu, Z. et al. Synthesis, crystal structure and thermal behavior of Rb(NTO) · H2O. Chin.Sci.Bull. 46, 45–48 (2001). https://doi.org/10.1007/BF03183207

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03183207

Keywords

Search

Navigation