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Chinese Science Bulletin

, Volume 48, Issue 20, pp 2180–2182 | Cite as

Photopromoted carbonylation of olefins with carbon dioxide and labelling studies with13CO2 and13CH3OH

  • Jingmei Yin
  • Dabin Gao
  • Jiehan Hu
  • Guangyun Zhou
  • Yingping Jia
  • Xiangsheng Wang
Reports

Abstract

Photopromoted carbonylation of olefins with carbon dioxide can be completed in ambient conditions (room temperatures and atmospheric pressure) by Co(OAc)2 catalysis. It was found that in carbonyl carbons of methyl ester of aliphatic acid 50% is from CO2 and the other 50% from CH3OH by labelling experimental with13CO2 and13CH3OH.

Keywords

photopromoted carbonylation carbon dioxide ambient conditions labelling studies with13CO2 and13CH3OH 

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References

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Copyright information

© Science in China Press 2003

Authors and Affiliations

  • Jingmei Yin
    • 1
    • 2
  • Dabin Gao
    • 2
  • Jiehan Hu
    • 3
  • Guangyun Zhou
    • 2
  • Yingping Jia
    • 2
  • Xiangsheng Wang
    • 1
  1. 1.State Key Laboratory of Fine ChemicalsDalian University of TechnologyDalianChina
  2. 2.Department of Chemistry & Chemical EngineeringDalian UniversityDalianChina
  3. 3.Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianChina

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