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Studies in the friedel-crafts reaction

Part VI. Further Evidence for γ-Substitution in the resorcinol and orcinol derivatives
  • R. D. Desai
  • V. M. Vakil
Article
  • 22 Downloads

Summary

Definite and conclusive evidence of simultaneous β- and γ-substitution or γ-substitution alone has been obtained in the case of the reactions between (1) orcinol and acetyl chloride; (2) β-orcacetophenone and acetic anhydride; (3) benzoyl chloride and resacetophenone; and (4) acetic anhydride and 4-benzoylresorcinol in presence of anhydrous AlCl3. The constitution of the resulting products have been established by their independent and rational synthesis.

Keywords

Nitrobenzene Acetic Anhydride Resorcinol Benzoyl Chloride Acetyl Chloride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Desai and EkhlasProc. Ind. Acad. Sci., (A), 1938,8, 194.Google Scholar
  2. 2.
    RasinskiJ. Pr. Chem. (2),26, 59.Google Scholar
  3. 3.
    HoeschBer., 1915,48, 1130.Google Scholar
  4. 4.
    BakerJ. 1933, 1384.Google Scholar
  5. 5.
    LimayeRasayanam, 1936,1, 66.Google Scholar

Copyright information

© Indian Academy of Sciences 1940

Authors and Affiliations

  • R. D. Desai
    • 1
  • V. M. Vakil
    • 1
  1. 1.Department of ChemistrySt. Xavier’s CollegeBombay

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