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Oxidation by chloramine-T

Part II. Redox potential of chloramine-T—Sulphonamide systems
  • A. R. Vasudeva Murthy
  • B. Sanjiva Rao
Article
  • 128 Downloads

Summary

Potentials of the chloramine-T—sulphonamide system have been found to be real redox potentials. With an increase in pH, the oxidation potential decreases. Depending on the pH of the solution, the oxidation of hydrogen sulphide by chloramine-T yields varying proportions of sulphur and sulphate. Reagents like osmic acid, sodium tungstate and sodium molybdate are also found to affect the ratio of sulphur to sulphate, formed by the oxidation of hydrogen sulphide.

A complete explanation for the observed results cannot be based on the effect of pH on the redox potential, as these reagents do not alter the potential. The specific effect of these reagents is probably due to their influence on dihydrogen sulphoxide, the primary product of oxidation of hydrogen sulphide.

Keywords

Redox Potential Borax Sulphonamide Hydrogen Sulphide Sodium Tungstate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. 1.
    Vasudeva Murthy, A. R. and Sanjiva Rao, B...Proc. Ind. Acad. Sci., 1952,35, 7.Google Scholar

Copyright information

© Indian Academy of Sciences 1952

Authors and Affiliations

  • A. R. Vasudeva Murthy
    • 1
  • B. Sanjiva Rao
    • 1
  1. 1.Indian Institute of ScienceBangalore

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