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Applied Magnetic Resonance

, Volume 30, Issue 3–4, pp 549–554 | Cite as

Specific MARY spectrum from radical anion of pentafluorobenzene

  • E. V. Kalneus
  • A. A. Kipriyanov
  • P. A. Purtov
  • D. V. Stass
  • Yu. N. Molin
Article

Abstract

The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system.

Keywords

Electron Spin Resonance Squalane Molin Magnetic Field Effect Pentafluorobenzene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer 2006

Authors and Affiliations

  • E. V. Kalneus
    • 1
    • 2
  • A. A. Kipriyanov
    • 1
    • 2
  • P. A. Purtov
    • 1
    • 2
  • D. V. Stass
    • 1
    • 2
  • Yu. N. Molin
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionRussian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation

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