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Specific MARY spectrum from radical anion of pentafluorobenzene

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Abstract

The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Institutskaya ulitsa 3, 630090, Novosibirsk, Russian Federation

    E. V. Kalneus, A. A. Kipriyanov, P. A. Purtov, D. V. Stass & Yu. N. Molin

  2. Novosibirsk State University, Novosibirsk, Russian Federation

    E. V. Kalneus, A. A. Kipriyanov, P. A. Purtov & D. V. Stass

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  1. E. V. Kalneus
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  2. A. A. Kipriyanov
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  3. P. A. Purtov
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  4. D. V. Stass
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  5. Yu. N. Molin
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Correspondence to E. V. Kalneus.

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Kalneus, E.V., Kipriyanov, A.A., Purtov, P.A. et al. Specific MARY spectrum from radical anion of pentafluorobenzene. Appl. Magn. Reson. 30, 549–554 (2006). https://doi.org/10.1007/BF03166217

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  • DOI: https://doi.org/10.1007/BF03166217

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