Applied Magnetic Resonance

, Volume 30, Issue 3–4, pp 549–554 | Cite as

Specific MARY spectrum from radical anion of pentafluorobenzene

  • E. V. Kalneus
  • A. A. Kipriyanov
  • P. A. Purtov
  • D. V. Stass
  • Yu. N. Molin


The paper presents the first resolved experimental magnetically affected reaction yield (MARY) spectrum for a system with nonequivalent nuclei, radical anion of pentafluorobenzene. This observation dispels the common apprehension that because of a rather involved energy level layout a system with not all nuclei magnetically equivalent cannot produce resolved MARY lines in nonzero fields, and greatly, increases the practical scope of level-crossing techniques for studies of spin-correlated radical pairs. The experimental finding is supported by schemes of energy levels calculated for this system.


Electron Spin Resonance Squalane Molin Magnetic Field Effect Pentafluorobenzene 
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Copyright information

© Springer 2006

Authors and Affiliations

  • E. V. Kalneus
    • 1
    • 2
  • A. A. Kipriyanov
    • 1
    • 2
  • P. A. Purtov
    • 1
    • 2
  • D. V. Stass
    • 1
    • 2
  • Yu. N. Molin
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionRussian Academy of SciencesNovosibirskRussian Federation
  2. 2.Novosibirsk State UniversityNovosibirskRussian Federation

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