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The study of the electron spin exchange efficiency in liquid solutions of radicals at various EPR frequencies

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Abstract

The electron spin exchange efficiency in toluene solutions of stable nitroxide radicals at different EPR frequencies has been studied. The experimental results are in good agreement with the theory. The spin exchange constantsK e measured at X-band and 2-mm band coincide. TheK e values measured from the exchange broadening of the EPR lines do not depend on the value of the nitrogen nuclear spinI N

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Kosygin str. 4, 117977, Moscow B-334, Russian Federation

    S. D. Chemerisov, A. I. Kokorin, O. Ya. Grinberg & Ya. S. Lebedev

Authors
  1. S. D. Chemerisov
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  2. A. I. Kokorin
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  3. O. Ya. Grinberg
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  4. Ya. S. Lebedev
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Chemerisov, S.D., Kokorin, A.I., Grinberg, O.Y. et al. The study of the electron spin exchange efficiency in liquid solutions of radicals at various EPR frequencies. Appl. Magn. Reson. 9, 37–43 (1995). https://doi.org/10.1007/BF03162345

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  • DOI: https://doi.org/10.1007/BF03162345

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