Abstract
The effect of the distribution of anisotropic hyperfine interaction on the cross peak line shape of protons in single crystal two-dimensional four-pulse electron spin echo envelope modulation spectra are discussed. The inclusion of an additional mixing pulse in the evolution period of the four-pulse sequence allows the simultaneous measurement of cross and sum peaks in a two-dimensional experiment. The sum peaks directly map the distribution of the anisotropic hyperfine interaction. As an experimental example the hyperfine interaction parameter distribution of protons localzed in hydrogen bonds of a mixed single crystal betaine phosphate/betaine phosphite is examined.
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Pöppl, A., Böttcher, R. & Völkel, G. Analysis of anisotropic hyperfine interaction distributions in two-dimensional four- and five-pulse electron spin echo envelope modulation spectra of protons in single crystals. Appl. Magn. Reson. 12, 15–39 (1997). https://doi.org/10.1007/BF03161988
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DOI: https://doi.org/10.1007/BF03161988