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The effect of rotation-vibrational interaction on the line intensities in the optical spectra of diatomic molecules

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Acta Physica Academiae Scientiarum Hungaricae

Abstract

Using perturbation calculation simple relations have been received that make possible to evaluate the appearance of rotation-vibrational interaction in the line intensity of gaseous diatomic molecules from a sufficient number of experimental data. The connection between the rotational temperature determined from the optical spectra neglecting rotation-vibrational interaction and the real rotational temperature of the gas has been found.

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References

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Authors and Affiliations

  1. Institute for High Temperatures, Moscow, USSR

    A. I. Kobylansky

Authors
  1. A. I. Kobylansky
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Kobylansky, A.I. The effect of rotation-vibrational interaction on the line intensities in the optical spectra of diatomic molecules. Acta Physica 45, 363–369 (1978). https://doi.org/10.1007/BF03158161

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  • DOI: https://doi.org/10.1007/BF03158161

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