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Studies in naphthalene series

Part VII. Attempted synthesis of 4-stearyl-, 4-palmityl-, and 4-lauryl-1-naphthols
  • R. D. Desai
  • W. S. Waravdekar
Article
  • 9 Downloads

Summary

4-Stearyl-1-naphthol is obtained in a poor yield by the Friedel-Crafts Reaction between stearyl chloride and α-naphthol as the main product is 2-stearyl-1-Naphthol. α-naphthylmethyl ether, however, gave an excellent yield of 1-methoxy-4-stearyl-naphthalene, but its demethylation by anhydrous aluminium chloride led to the simultaneous removal of the stearyl group. Clemmenson Reduction gave readily 1-methoxy-4-octadecyl-naphthalene. Similar results were obtained by using palmityl and lauryl chlorides.

Keywords

Nitrobenzene Ferric Chloride Methyl Ether Stearyl Palmityl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Akram and DesaiProc. Ind. Acad. Sci., (A), 1940,11, 149. Desai and WaravdekarIbid. Proc. Ind. Acad. Sci., (A), 1940,12, 507.Google Scholar
  2. 2.
    Clemo, Cockburn and SpenceJ., 1931, 1265.Google Scholar

Copyright information

© Indian Academy of Sciences 1941

Authors and Affiliations

  • R. D. Desai
    • 1
  • W. S. Waravdekar
    • 1
  1. 1.Chemistry DepartmentSt. Xavier's CollegeBombay

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