Skip to main content
SpringerLink
Log in

Kinetic parameters from chronopotentio-metric waves

  • Published:
Proceedings of the Indian Academy of Sciences - Section A Aims and scope Submit manuscript

Abstract

A simplified expression is given for the potential-time relation of a cathodic chronopotentiometric wave which involves mixed control by diffusion and charge-transfer. The treatment of quasi-reversible chronopotentiometric waves has been considered in detail. The chronopotentiometric behaviour of a number of partially irreversible and totally irreversible systems has been studied. The kinetic parameters have been evaluated and compared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Karaoglanoff, Z...Z. Elektrochem., 1906,12, 5.

    Article  Google Scholar 

  2. Delahay, P. and Berzins, T.J. Am. Cftem. Soc., 1953,75, 2486.

    Article  Google Scholar 

  3. Berzins, T. and Delahay, P.Ibid., 1955,77, 6448.

    Article  Google Scholar 

  4. Anderson, L. B. and Macero, D. J.Anal. Chem., 1965,37, 322.

    Article  Google Scholar 

  5. Delahay, P...New Instrumental Methods In Electrochemistry, Interscience Publishers, Inc., New York, 1954, p. 180.

    Google Scholar 

  6. Sand, H. J. S...Phil. Mag., 1901,1, 45.

    Google Scholar 

  7. Oldham, K. B...Electrochim. Acta, 1966,11, 1475.

    Article  Google Scholar 

  8. Chandrasekharan, V. R., Sundaresan, R., Saraiya, S. C. and Radhakrishnan, T. P.Report B.A.R.C-370. 1968., p. 8.

  9. Delahay, P. and Mattax, C. C.J. Am. Chem. Soc., 1954,76, 874.

    Article  Google Scholar 

  10. Reinmuth, W. H...Anal. Chem., 1961,33, 485.

    Article  Google Scholar 

  11. Reilly, C. N., Everett, G. W. and Johns, R. H.Ibid., 1955,27, 483.

    Article  Google Scholar 

  12. Anne Marie Baticle, C. R.Acad. Sci., Paris, 1962,254, 668.

    Google Scholar 

  13. Sundaresan, R., Saraiya, S. C. and Sundaram, A. K.Proc. Ind. Acad. Sci., 1967,66 (2), 120.

    Google Scholar 

  14. Matsuda, H. and Ayabe, Y.Z. Elektrochem., 1959,63, 1164.

    Google Scholar 

  15. —,—and Adachi, K.Ibid., 1963,67, 593.

    Google Scholar 

  16. Randles, J. E. B. and Somerton, K. W.Trans. Farad. Soc., 1952,48, 937.

    Article  Google Scholar 

  17. Moussa, A. A. and Sammour, H. M.J. Chem. Soc., 1960, p. 2151.

  18. Satyanarayana, S...J. Electroanal. Chem., 1964,7, 403.

    Article  Google Scholar 

  19. Gierst, L. and Cornellissen, R.Coll. Czech. Chem. Comm., 1960,25, 3004.

    Google Scholar 

  20. Gierst, L. ..Trans. Symp. Electrode Proc. Philadelphia, 1959, p. 109.

  21. Saraby-Reintjes, A. and Overbeek, J. TH. G.Trans. Farad. Soc., 1966,62, 182.

    Article  Google Scholar 

  22. Randies, J. E. B...Can. J. Chem., 1959,37, 238.

    Article  Google Scholar 

  23. Timmer, B., Sluyters-Rehbach, M. and Sluyters, J. H.J. Electroanal. Chem., 1967,14, 181.

    Article  Google Scholar 

  24. Latimer, W. M...Oxidation Potentials, Prentice-Hall, Inc., N.J., 1959.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Analytical Division, Bhabha Atomic Research Centre, Modular Laboratories, Trombay, Bombay-85 AS

    T. P. Radhakrishnan & A. K. Sundaram

Authors
  1. T. P. Radhakrishnan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. K. Sundaram
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Radhakrishnan, T.P., Sundaram, A.K. Kinetic parameters from chronopotentio-metric waves. Proc. Indian Acad. Sci. 75, 278–293 (1972). https://doi.org/10.1007/BF03049760

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03049760

Keywords

Search

Navigation