Advertisement

Kinetics of the thallic ion oxidation of olefins

  • Nrusingha C. Khandual
  • Kamala K. Satpathy
  • P. L. Nayak
Article
  • 18 Downloads

Abstract

The kinetics of oxidation of chalkone (phenyl styryl ketone) and cinnamaldehyde by T1 (III) acetate in aqueous acetic acid is of the first order in olefin and first order with respect to the oxidant. The parameters of the transition state theory have been computed. The rate of the reaction is strongly accelerated by increasing acid concentration. The reaction rate is also retarded by added sodium chloride and sodium acetate. The results have been interpreted in the light of the ionic mechanism considering T1 (OAc)3 to be the active oxidant in aqueous acetic acid.

Keywords

Thallium Cinnamaldehyde Norbornene Transition State Theory Aqueous Acetic Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Patnaik, A. K., Nayak, P. L. and Rout, M. K.Ind. J. Chem., 1970,8, 722;Google Scholar
  2. 1a.
    Satpathy, K. K., Patnaik, A. K., Nayak, P. L. and Rout, M. K.J. Ind. Chem. Soc., 1971,48, 847;Google Scholar
  3. 1b.
    Nayak, P. L. and Rout, M. K.Ibid., 1971,63, 32.Google Scholar
  4. 2.
    Meyer, R. J. and Goldschmidt, E.Ber., 1903,36, 238.Google Scholar
  5. 3.
    Hecker, E. and Lattrett, R.Ann., 1963, p. 48.Google Scholar
  6. 4.
    Glushkova, V. P. and Kocheshkov, K. A.Bull. Akad. Nauk. SSSR, 1957, p. 1211.Google Scholar
  7. 5.
    Kabbe, H. J.Ann., 1962,656, 204;Google Scholar
  8. 5a.
    Grinstead, R. R.Org. Chem., 1961,26, 656;CrossRefGoogle Scholar
  9. 5b.
    Anderson, C. B. and Winstein, S.J. Org. Chem., 1963,28, 605.CrossRefGoogle Scholar
  10. 6.
    Glushkov, V. P. and Kocheshko, K. A.Izu. Akad. Nauk. SSSR, Otd. Khim. Nauk, 1957, p. 1193Google Scholar
  11. 6a.
    Glushkova, V. P. and Kocheshko, K. A.Bull. Akad. Nauk. SSSR, 1957, p. 1217.Google Scholar
  12. 7.
    Henry, P. M.J. Amer. Chem. Soc., 1965,87, 990; 1965,87, 4423; 1966,88, 1597.CrossRefGoogle Scholar
  13. 8.
    Kobbe, K. J. LeibigsAnn., 1962,656, 204.Google Scholar
  14. 9.
    South, A. (Jr.) and Ouellette, R. J.J. Amer. Chem. Soc., 1968,90, 7064;CrossRefGoogle Scholar
  15. 9a.
    Ouellette, R. J., Kordosky, G., Levin, C. and Williams, S.J. Org. Chem., 1969,34, 4105.Google Scholar
  16. 10.
    Rout, N., Nayak, P. L. and Rout, M. K.J. Ind. Chem. Soc., 1970, 217.Google Scholar
  17. 11.
    Mallick, M. N. and Das, M. N.Tetrahedron, 1963,19, 1981–87;CrossRefGoogle Scholar
  18. 11a.
    J. Amer. Chem. Soc., 1960,82, 4269.CrossRefGoogle Scholar
  19. 12.
    Bjerrum, Schwarzenbach, and Sillen, L. G.Stability Constants, Part II: Inorganic Ligands, The Chemical Society, Burlinghon House, W-1, London, 1958.Google Scholar
  20. 13.
    Sykes, A. G.Kinetics of Inorganic Reactions, Pergamon Press, Oxford, 1966, p. 147.Google Scholar
  21. 14.
    Anderson, C. B. and Winstein, S.J. Org. Chem., 1963,28, 605.CrossRefGoogle Scholar
  22. 15.
    Lee, J. B. and Price, M. J.Tetrahedron Letters, 1962,24, 1155.CrossRefGoogle Scholar
  23. 16.
    Anderson, M. M. and Henry, P. M.Chem. Ind. (London), 1961, p. 2053.Google Scholar
  24. 17.
    Traylor, T. G. and Baker, A. W.Tetrahedron Letters, 1959,14(19).Google Scholar
  25. 18.
    Schubert, W. M. B. Lamm and Keefa, J. R.J. Am. Chem. Soc., 1964,86, 4728.Google Scholar

Copyright information

© Indian Academy of Sciences 1972

Authors and Affiliations

  • Nrusingha C. Khandual
    • 1
  • Kamala K. Satpathy
    • 1
  • P. L. Nayak
    • 1
  1. 1.Department of ChemistryRavenshaw CollegeCuttack-3

Personalised recommendations