Paramagnetic resonance of Mn²⁺ in KNO₃ single crystal: Motional effects

Abstract

The electron paramagnetic resonance of Mn²⁺ in KNO₃ single crystal is investigated over a temperature cycle through transition temperatures. The hyperfine coupling constant, A, half width,Δ H, and the line intensity, I, are found to show sudden changes at the transition temperature, at whichα-KNO₃ changes intoβ-KNO₃. The lines are much sharper in the high temperatureβ-phase than inα-phase of the crystal. They are explained, qualitatively, in terms of structure change and rotation of NO ⁻₃ ions. The spectra in the two phases,α andβ, are analysed in terms of usual spin-Hamiltonian. A search of metastableγ-phase is also made and probable indications for the same are found.