Advertisement

Research on Chemical Intermediates

, Volume 34, Issue 8–9, pp 827–833 | Cite as

Preparation, characterization and catalytic activity of Bi−Mo-based catalysts for the oxidative dehydrogenation ofn-butene to 1,3-butadiene

  • Ji Chul Jung
  • Howon Lee
  • Heesoo Kim
  • Young-Min Chung
  • Tae Jin Kim
  • Seong Jun Lee
  • Seung-Hoon Oh
  • Yong Seung Kim
  • In Kyu Song
Article

Abstract

Multicomponent bismuth molybdates were prepared by a co-precipitation method for use in the oxidative dehydrogenation ofn-butene to 1,3-butadiene. The effect of divalent and trivalent metals on the catalytic performance of multicomponent bismuth molybdate catalysts was investigated. It was found that the metal ratio of Fe/Bi/Mo=3∶1∶12 was favorable for the reaction. The successful formation of Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts was well confirmed by XRD and ICP-AES measurements. The multicomponent bismuth molybdate catalysts showed a better catalytic performance than the pure γ-Bi2MoO6 catalyst. Among the Ni X Co8−X Fe3Bi1Mo12O50 (X=0−8) catalysts, Ni3Co5Fe3Bi1Mo12O50 showed the highest yield of 1,3-butadiene.

Keywords

Multicomponent bismuth molybdate n-butene 1,3-butadiene oxidative dehydrogenation 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Ph. A. Batist, J. F. H. Bouwens and G. C. A. Schuit,J. Catal. 25, 1 (1972).CrossRefGoogle Scholar
  2. 2.
    A. P. V. Soares, L. D. Dimitrov, M. C. A. Oliveira, L. Hilaire, M. F. Portela and R. K. Grasselli,Appl. Catal. A 253, 191 (2003).CrossRefGoogle Scholar
  3. 3.
    M. Egashira, K. Matsuo, S. Kagawa and T. Seiyama,J. Catal. 58, 409 (1979).CrossRefGoogle Scholar
  4. 4.
    Y. Moro-oka and W. Ueda,Adv. Catal. 40, 233 (1994).CrossRefGoogle Scholar
  5. 5.
    M. W. J. Wolfs and Ph. A. Batist,J. Catal. 32, 25 (1974).CrossRefGoogle Scholar
  6. 6.
    D.-H. He, W. Ueda and Y. Moro-oka,Catal. Lett. 12, 35 (1992).CrossRefGoogle Scholar
  7. 7.
    Ph. A. Batist, A. H. W. M. Der Kinderen, Y. Leeuwenburgh, F. A. M. G. Metz and G. C. A. Schuit,J. Catal. 12, 45 (1968).CrossRefGoogle Scholar
  8. 8.
    E. Ruckenstein, R. Krishnan and K. N. Rai,J. Catal. 45, 270 (1976).CrossRefGoogle Scholar
  9. 9.
    H. H. Kung and M. C. Kung,Adv. Catal. 33, 159 (1985).CrossRefGoogle Scholar
  10. 10.
    B. Grzybowska, J. Haber and J. Komorek,J. Catal. 25, 25 (1972).CrossRefGoogle Scholar
  11. 11.
    J. C. Jung, H. Kim, A. S. Choi, Y.-M. Chung, T. J. Kim, S. J. Lee, S.-H. Oh and I. K. Song,J. Mol. Catal. A 259, 166 (2006).CrossRefGoogle Scholar

Copyright information

© Springer 2008

Authors and Affiliations

  • Ji Chul Jung
    • 1
  • Howon Lee
    • 1
  • Heesoo Kim
    • 1
  • Young-Min Chung
    • 2
  • Tae Jin Kim
    • 2
  • Seong Jun Lee
    • 2
  • Seung-Hoon Oh
    • 2
  • Yong Seung Kim
    • 2
  • In Kyu Song
    • 1
  1. 1.School of Chemical and Biological Engineering, Institute of Chemical ProcessesSeoul National UniversitySeoulSouth Korea
  2. 2.SK CorporationDaejeonSouth Korea

Personalised recommendations