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Intermolecular charge-transfer forces

Conferenza tenuta il 29 maggio 1953

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Summary

In this lecture is described a new type of cohesive force between molecules. The fondamental idea is the use of a quantum mechanical description.

Many applications are illustrated and in particular, those who interest intermolecular forces in liquids and molecular crystals and elettrical spectroscopic properties of solution and crystals.

Riassunto

Viene descritto un nuovo tipo di forza di coesione tra molecole, dovuto a trasferimento intermolecolare di cariche. L’idea fondamentale viene sviluppata secondo la meccanica quantistica con un formalismo matematico particolarmente semplice, che tuttavia porta a risultati notevolissimi. Si esaminano in dettaglio alcuni casi e si accenna ad applicazioni del metodo allo studio dei liquidi e dei cristalli molecolari, e dette proprietà elettriche e spettroscopiche di soluzioni e cristalli.

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For further details, one may refer to R. S. Mulliken,J. Am. Chem. Soc. 72, 600 (1950); 74, 811 (1952);J. Phys. Chem. 56, 801 (1952). See also Paper N. 25 in ONR Report on September, 1951, Conference on «Quantum-Mechanical Methods in Valence Theory», issued by the Office of Naval Research, Department of Navy, Washington 25, D. C.

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Mulliken, R.S. Intermolecular charge-transfer forces. Seminario Mat. e Fis. di Milano 24, 183–189 (1954). https://doi.org/10.1007/BF02922542

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