Metal-containing monomers. Part 2. Preparation of polytetrafluoroethylene-grafted copper(II) chelate polymers and their use as lubricants
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The synthesis of copper(II) chelate monomers by the interaction of copper acrylate with 2,2′-bipyridyl or 1,10-phenanthroline has been developed. The complexes have been characterised by physico-chemical and spectroscopic measurements. New polymers containing copper chelate units have been prepared by post-grafting polymerization of these monomers onto a polytetrafluoroethylene surface. The lubricating effects of the immobilised complexes have been investigated.
KeywordsPhen PTFE Bipy Bipyridyl Transition Meet
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