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Chemical and antifungal properties of the nickel(II) complexes of 2-formylpyridine4 N-methyl-,4 N-dimethyl-,4 N-diethyl- and4 N-dipropylthiosemicarbazones

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Summary

Nickel(II) complexes of 2-formylpyridine4 N-methyl-,4 N-dimethyl-,4 N-diethyl- and4 N-dipropylthiosemicarbazones having approximately octahedral, planar and tetrahedral stereochemistry have been prepared and characterized spectroscopically.1H-n.m.r. of the thiosemicarbazones and a diamagnetic nickel complex are reported as well as the thiosemicarbazones’13C-n.m.r. spectra. The nickel(II) complexes show no growth inhibitory activity againstAspergillus niger, but have considerable activity againstPaecilomyces variotii, decreasing with increasing size of the ligand.

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Authors and Affiliations

  1. Department of Chemistry, Illinois State University, 61761, Normal, IL, USA

    Douglas X. West & Jill S. Saleda

  2. Department of Biological Sciences, Illinois State University, 61761, Normal, IL, USA

    Anthony E. Liberta

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  1. Douglas X. West
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  2. Jill S. Saleda
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  3. Anthony E. Liberta
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TMC 2713

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West, D.X., Saleda, J.S. & Liberta, A.E. Chemical and antifungal properties of the nickel(II) complexes of 2-formylpyridine4 N-methyl-,4 N-dimethyl-,4 N-diethyl- and4 N-dipropylthiosemicarbazones. Transition Met. Chem. 17, 568–572 (1992). https://doi.org/10.1007/BF02910760

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  • DOI: https://doi.org/10.1007/BF02910760

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