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Cyclic ligands with fixed coordination geometry, Part 8(1). Structure of [CuCl(Vn3S3)]·2THF and of [CuCl(Me2S)3] for comparison (Vn3S3 = 5,10,15-trithia-cyclo-triveratrylene)

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Summary

[CuCl(Vn3S3)]·2THF (8) and [CuCl(Me2S)3] (9) can directly be obtained by reacting copper (I) chloride either with 5,10,15-trithia-cyclo-triveratrylene (Vn3S3) in a 1∶1 molar ratio in tetrahydrofuran (THF) as a solvent or in an excess of dimethylsulphide (Me2S). In both complexes the copper ion has a tetrahedral coordination which is, however, strongly distorted in the case of (8) because of the fixed geometry of the Vn3S3 ligand (mean values: Cl−Cu−S 124.1° and 110.2°, S−Cu−S 91.7° and 108.7°). In spite of similar Cu−S distances [232.2(2) and 231.2(3)pm] the donor ability of Vn3S3 is not as good as that of three Me2S ligands due to the less optimal bond angles formed in (8); consequently, in (8) the Cu−Cl distance is significantly shorter than in (9) [220.4(2) versus 226.3(3) pm].

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References

  1. Part 7: J. Behrens, S. ARnold, G. Klar and W. Hinrichs,Transition Met. Chem.,16, 76 (1991).

    Article  CAS  Google Scholar 

  2. C. J. Pedersen,J. Am. Chem. Soc.,89, 7017 (1967);92, 386 and 391 (1970).

    Article  CAS  Google Scholar 

  3. W. Rosen and D. H. Busch,Inorg. Chem.,9, 262 (1970).

    Article  CAS  Google Scholar 

  4. L. A. Ochrymowycz, C.-P. Mak and J. D. Michna,J. Org. Chem.,39, 2079 (1974).

    Article  CAS  Google Scholar 

  5. W. N. Setzer, C. A. Ogle, G. S. Wilson and R. S. Glass,Inorg. Chem.,22, 266 (1983).

    Article  CAS  Google Scholar 

  6. R. J. Batchelor, F. W. B. Einstein, I. D. Gay, J.-H. Gu, B. D. Johnston and B. M. Pinto,J. Am. Chem. Soc.,111, 6582 (1989).

    Article  CAS  Google Scholar 

  7. K. von Deuten and G. Klar,Cryst. Struct. Commun.,10, 757 and 765 (1981).

    Google Scholar 

  8. K. von Deuten and G. Klar,Z. Naturforsch.,36b, 1526 (1981).

    Google Scholar 

  9. K. von Deuten, J. Kopf and G. Klar,Cryst. Struct. Commun.,8, 721 (1979).

    Google Scholar 

  10. J. Kopf, K. von Deuten and G. Klar,Cryst. Struct. Commun.,8, 1011 (1979).

    CAS  Google Scholar 

  11. N. Walker and D. Stuart,Acta Crystallogr.,A39, 158 (1983).

    Article  Google Scholar 

  12. G. M. Sheldrick, SHELXS-86,Programs for crystal structure solution, Universität Göttingen, 1986.

  13. G. M. Sheldrick, SHELX-76,Program for crystal structure determination, University of Cambridge, England, 1976.

    Google Scholar 

  14. T. Weiss and G. Klar,Z. Naturforsch.,34b, 448 (1979).

    CAS  Google Scholar 

  15. J. S. Filipo, Jr., L. E. Zyontz and J. Potenza,Inorg. Chem.,14, 1667 (1975).

    Article  Google Scholar 

  16. H. O. House, C.-Y. Chu, J. M. Wilkins and M. J. Umen,J. Org. Chem.,40, 1460 (1975).

    Article  CAS  Google Scholar 

  17. Handbook of Chemistry and Physics, 58th Edit., CRC-Press, Cleveland, Ohio, 1977–1978, p. D-178.

  18. H.-J. Küppers, K. Wieghardt, Y.-H. Tsay, C. Krüger, B. Nuber and J. Weiss,Angew. Chem.,99, 583 (1987);Angew. Chem., Int. Ed.,26, 575 (1987).

    Article  Google Scholar 

  19. M. M. Olmstead, W. K. Musker and R. M. Kessler,Transition Met. Chem.,7, 140 (1982).

    Article  CAS  Google Scholar 

  20. A. Domenicano, R. Spagna and A. Vaciago,J. Chem. Soc., Part D (Chem. Commun.), 1146 (1970).

  21. W. Hinrichs, H.-J. Riedel and G. Klar,J. Chem. Research, (S) 334, (M) 3501 (1982).

    Google Scholar 

  22. J. Kaiser, G. Brauer, F. A. Schröder, I. F. Taylor and S. E. Rasmussen,J. Chem. Soc., Dalton Trans., 1490 (1974).

  23. J. A. Tiethof, J. K. Stalick and D. W. Meek,Inorg. Chem.,12, 1170 (1973).

    Article  CAS  Google Scholar 

  24. L. P. Battaglia, A. Bonamartini Corradi, M. Nardelli and M. E. Vidoni Tani,J. Chem. Soc., Dalton Trans., 143 (1976).

  25. E. W. Ainscough, H. A. Bergen, A. M. Brodie and K. A. Brown,J. Chem. Soc., Dalton Trans., 1649 (1976).

  26. M. Barrow, H. B. Bürgi, D. K. Johnson and L. M. Venanzi,J. Am. Chem. Soc.,98, 2356 (1976).

    Article  CAS  Google Scholar 

  27. G. W. Hunt, E. A. H. Griffith and E. L. Amma,Inorg. Chem.,15, 2993 (1976).

    Article  CAS  Google Scholar 

  28. C. J. de Ranter and M. Rolies,Cryst. Struct. Commun.,6, 399 (1977).

    Google Scholar 

  29. C. Brink and C. H. MacGillavry,Acta Crystallogr.,2, 158 (1949).

    Article  CAS  Google Scholar 

  30. C. Brink and A. E. van Arkel,Acta Crystallogr.,5, 506 (1952).

    Article  Google Scholar 

  31. R. L. Girling and E. L. Amma,Inorg. Chem.,10, 335 (1971).

    Article  Google Scholar 

  32. V. G. Albano, P. L. Bellon and G. Ciani,J. Chem. Soc., Dalton Trans., 1938 (1972).

  33. F. A. Cotton, B. A. Frenz, D. L. Hunter and Z. C. Mester,Inorg. Chim. Acta,11, 111 (1974).

    Article  CAS  Google Scholar 

  34. D. L. Dunning, B. L. Kindberg, C. F. Plese, E. H. Griffith and E. L. Amma,J. Chem. Soc., Chem. Commun., 550 (1975).

  35. A. L. Shoemaker, P. Singh and D. J. Hodgson,Acta Crystallogr.,B32, 979 (1976).

    Google Scholar 

  36. J. T. Gill, J. J. Mayerle, P. S. Welcker, D. F. Lewis, D. A. Ucko, D. J. Barton, D. Stowens and S. J. Lippard,Inorg. Chem.,15, 1155 (1976).

    Article  CAS  Google Scholar 

  37. D. Gatteschi, C. Mealli and L. Sacconi,Inorg. Chem.,15, 2774 (1976).

    Article  CAS  Google Scholar 

  38. A. T. H. Lenstra, S. Tavernier and W. Versichel,Bull. Soc. Chim. Belg.,86, 419 (1977).

    CAS  Google Scholar 

  39. A. Pignedoli and G. Peyronel,Acta Crystallogr.,B35, 2009 (1979).

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Institut für Anorganische und Angewandte Chemie der Universität Hamburg, Martin-Luther-King-Platz 6, W-2000, Hamburg 13, Germany

    Falk Olbrich, Harald Maelger & Günter Klar

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  1. Falk Olbrich
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  2. Harald Maelger
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  3. Günter Klar
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TMC 2725

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Olbrich, F., Maelger, H. & Klar, G. Cyclic ligands with fixed coordination geometry, Part 8(1). Structure of [CuCl(Vn3S3)]·2THF and of [CuCl(Me2S)3] for comparison (Vn3S3 = 5,10,15-trithia-cyclo-triveratrylene). Transition Met. Chem. 17, 525–529 (1992). https://doi.org/10.1007/BF02910749

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