Abstract
Dynamic effect on the fine structure of X-ray photoelectron spectra of lanthanide oxides and fluorides is discussed. The Ln4p electron spectra are considerably complicated by the interaction between the configurations of themain one-hole and additional two-hole final states of 4p54d54fn ↔ 4p64d8fn+1 type. The effect of the nature of atoms in the nearest environment of lanthanide ions on the fine structure parameters is evaluated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. S. Bagus, A. J. Freeman, and F. Sasaki,Phys. Rev. Lett.,30, No. 18, 850–853 (1973).
P. S. Bagus, A. J. Freeman, and F. Sasaki,Int. J. Quant. Chem. Symp., No. 7, 83–92 (1973).
E.-K. Viinikka and Y. Ohrn,Phys. Rev. B,11, No. 11, 4168–4175 (1975).
V. F. Demekhin, V. L. Sukhorukov, T. V. Shelkovich, et al.,Zh. Strukt. Khim.,20, No. 1, 38–48 (1979).
Yu. A. Teterin, A. S. Baev, V. M. Kulakov, et al.,Abstracts of Papers from the Conference “X-Ray and X-Ray Photoélectron Spectra and Electronic Structure of Metals, Alloys, and Chemical Compounds,” Izhevsk (1979).
G. Wendin,Struct. Bond.,41, 1–122 (1981).
Yu. A. Teterin, A. S. Baev, Yu. P. Dikov, and A. I. Gorshkov,Dokl. Akad. Nauk SSSR,263, No. 3, 610–615 (1982).
V. L. Sukhorukov, S. A. Yavna, V. F. Demekhin, and B. M. Lagutin,Koordinats. Khim.,11, No. 4, 510–515 (1985).
V. L. Sukhorukov, I. D. Petrov, V. M. Lagutin, et al.,ibid.,12, No. 2, 205–206 (1986).
U. C. Sing, D. D. Sarma, and C. N. R. Rao,Chem. Phys. Lett.,85, 278–282 (1982).
K. Siegbahn, K. Nordling, A. Fahlman, et al.,ESCA, Atomic, Molecular, and Solid State, Nova Ada Regiae Societatis Scientarium Upsaliensis, Ser. IV, Vol. 20,Structure Studied by Means of Electron Spectroscopy, Uppsala (1967).
Yu. A. Teterin, A. S. Baev, S. G. Gagarin, and V. D. Klimov,Radiokhim.,27, No. 1, 3–13 (1985).
Yu. A. Teterin, V. M. Kulakov, A. S. Baev, et al.,Phys. Chem. Miner.,7, 151–158 (1981).
S. P. Kowalczyk, L. Ley, R. L. Martin, et al.,Faraday Discuss. Chem. Soc,60, 7 (1975).
M. Ohno and R. E. La Villa,Phys. Rev. B,39, No. 13, 8852–8857 (1989).
J. H. Scofield,J. Electron. Spectrosc. Relat. Phenom.,8, 129–137 (1976).
Yu. A. Teterin, A. S. Baev, and S. G. Gagarin,Radiokhim.,28, No. 3, 318–328 (1986).
F. P. Larkins,Atom. Data Nucl. Data Tables,20, No. 4, 311–387 (1977).
V. L. Sukhorukov, S. A. Yavna, and V. F. Demekhin,Fiz. Tverd. Tela,26, No. 7, 2172–2175 (1984).
B. D. Padalia, W. C. Lang, P. R. Norris, et al.,Proc. R. Soc. Lond.,A354, 269–290 (1977).
Author information
Authors and Affiliations
Additional information
Translated fromZhurnal Struktumoi Khimii, Vol. 39, No. 6, pp. 1059–1066, November–December, 1998.
Rights and permissions
About this article
Cite this article
Teterin, Y.A., Teterin, A.Y., Lebedev, A.M. et al. Dynamic effect on the structure of X-ray photoelectron spectra of lanthanide fluorides and oxides. J Struct Chem 39, 869–875 (1998). https://doi.org/10.1007/BF02903596
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02903596