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Chinese Science Bulletin

, Volume 46, Issue 13, pp 1061–1066 | Cite as

Supermolecular layered double hydroxides

  • Hu Changwen
  • Li Danfeng
  • Guo Yihang
  • Wang Enbo
Notes

Abstract

Research progresses in the layered double hydroxides [M (1-x )/2+ M x 3+ (OH)2] x+ A x n/n− ·mH2O intercalated with metal coordinate ions or oxometalates in the last ten years are reviewed. These layered double hydroxides are mainly intercalated with polyoxometalate (POM) ions, a LiAl-LDH photochemical assembly containing TiO2 and CH3(CH2)12COO anions, together with Zn(TPPC) (porphyrin derivate) and macrocyclic ligand-containing porphyrin derivate anions. Emphasis is put on the synthesis methods for intercalation of the anions into the interlayer regions, the characterization techniques and structures for the layered compounds and the newest research progress in the fields such as catalysis. The review also forecasts the prospects of the field.

Keywords

layered double hydroxide polyoxometalate synthesis structure property supermolecule 

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References

  1. 1.
    Hu, C. W., He, Q. L., Wang, E. B., Recent advances in pillaring layered double hydroxides by polyoxometalate anion, Prog. Natur. Sci., 1996, 6(5): 524.Google Scholar
  2. 2.
    Elizabeth, A. G., Yun, S. K., Pinnavaia, T. J. et al., Layered double hydroxides pillared by macropolyoxometalates, Appl. Clay. Sci., 1998, 13: 479.CrossRefGoogle Scholar
  3. 3.
    Lehn, J. M., Supramolecular chemistry-scope and perspectives molecules, supermolecules and molecular devices (Nobel Lecture), Agew. Chem. Int. Ed. Engl., 1988, 27: 89.CrossRefGoogle Scholar
  4. 4.
    Cavani, F., Trifiro, F., Vaccari, A., Hydrotalcite-type anionic clay: preparation and application, Catal. Today, 1991(11): 173.Google Scholar
  5. 5.
    Roy, A. D., Forano, C., Besse, J. P. et al., Synthesis of Microporous Materials (eds. Occelli, M. L., Robson, H. E.), New York: Van Nostrand Reinhold, Vol. II, 1992, 108–169.Google Scholar
  6. 6.
    Yun, S. K., Constantino, V. R. L., Pinnavaia, T. J., New polyol routes to Keggin ion-pillared layered double hydroxides, Microporous Mater., 1995, 4(1): 21.CrossRefGoogle Scholar
  7. 7.
    Drezdzon, M. A., Synthesis of isopolymetalate-pillared hydrotalcite via organic-anion-pillared precursors, Inorg. Chem., 1988, 27: 4628.CrossRefGoogle Scholar
  8. 8.
    Guo, J., Jiao, Q. Z., Min, E. Z. et al., Catalytic oxidation of cyclohexene with molecular oxygen by polyoxometalate-intercalated hydrotalcites, Catal. Lett., 1996, 40: 43.CrossRefGoogle Scholar
  9. 9.
    Hu, C. W., Wang, E. B., Misono, M. et al., Synthesis and oxiditive activity of polyoxometalate pillared anionic clays Zn2Al-SiW11 and Zn2Al-SiW11Z, Catal. Today, 1996, 30: 141.CrossRefGoogle Scholar
  10. 10.
    Guo, Y. H., Li, D. F., Hu, C. W. et al., Photocatalytic degradation of aqueous organocholorine pesticide on paratungstate A-intercalated layered double hydroxide [Mg12Al6(OH)36(W7O24) · 4H2O], Appl. Catal. B: Environmental, 2001, 30(3–4): 337.CrossRefGoogle Scholar
  11. 11.
    Kwon, T., Pinnavaia, T. J., Synthesis and properties of anionic clays pillared by [XM12O40]n- Keggin ions, J. Mol. Catal., 1992, 74:23CrossRefGoogle Scholar
  12. 12.
    Narita, E., Kaviratna, P. D., Pinnavaia, T. J., Synthesis of heteropolyoxometalate pillared layered double hydroxides via calcined zinc-aluminum oxide precursors, Chem. Lett., 1991(5): 805.Google Scholar
  13. 13.
    Liu, Y. Y., Hu, C. W., Wang, E. B. et al., Synthesis, characterization and catalytic reactivities of heteropolyanion-pillared clay of anions of Zn-Al type, Science in China, Ser. B, 1996, 39(1): 86.Google Scholar
  14. 14.
    Crepaldi, E. L., Pavan, P. C., Valim, J. B. et al., A new method of intercalation by anion exchange in layered double hydroxides, J. Chem. Soc. Chem. Commun., 1999, 2: 155.Google Scholar
  15. 15.
    Liu, J. G., Guo, J., Sun, T. et al., Studies on the interaction between the layers and pillars of hydrotalcite-like compounds pillared with heteropolyanions, Chem. J. Chin. Univ. (in Chinese), 1995, 16(9): 1329.Google Scholar
  16. 16.
    Hu, C. W., Zhang, X., Wan, E. B. et al., The rapid synthesis of heteropolyoxometalate pillared layered double hydroxide Zn2Al(OH)6[SiW11O39Co(H2O)]1/6 · 4H2O under the action of ultrasound, Trans. Met. Chem., 1997(22): 197.Google Scholar
  17. 17.
    Kwon, T., Pinnavaia, T. J., Pillaring of a layered double hydroxide by polyoxometalate with Keggin-ion, Chem. Mater., 1989(1): 381.Google Scholar
  18. 18.
    Narita, E., Kaviratna, P. D., Pinnavaia, T. J., Direct synthesis of a polyoxometalate-pillared layered double hydroxide by coprecipitation, J. Chem. Soc. Chem. Commun., 1993(1): 60.Google Scholar
  19. 19.
    Evans, J., Pillinger, M., Zhang, J., Structural studies of polyoxometalate-anion-pillared layered double hydroxides, J. Chem. Soc., Dalton Trans, 1996, 14:2963.CrossRefGoogle Scholar
  20. 20.
    Weir, M. R., Moore, J., Kydd, R. A., Effects of pH and Mg:Ga ratio on the synthesis of gallium-containing layered double hydroxides and their polyoxometalate anion exchanged products, Chem. Mater., 1997, 9: 1686.CrossRefGoogle Scholar
  21. 21.
    Yun, S. K., Pinnavaia, T. J., Layered double hydroxides intercalated by polyoxometalate anions with Keggin (α-H2W12O40 6-), Dawson (α-P2W18O62 26−), and Finke (Co4(H2O)(PW9O34)2 10−) structures, Inorg. Chem., 1996, 35: 6853.PubMedCrossRefGoogle Scholar
  22. 22.
    Dutta, P. K., Twu, J., Structure and reactivity of oxovanadate anions in layered lithium aluminate materials, J. Phys. Chem., 1989(93): 7864.Google Scholar
  23. 23.
    Kooli, F., Rives, V., Ulibarri, M. A., Preparation and study of decavanadate-pillared hydrotalcite-like anionic clays containing transition metal cations in the layers (1)—Samples containing nickel-aluminum prepared by anionic exchange and reconstruction, Inorg. Chem., 1995, 34: 5114.CrossRefGoogle Scholar
  24. 24.
    Barriga, C., Jones, W., Ulibarri, M. A. et al., Synthesis and characterization of polyoxovanadate-pillared Zn-Al layered double hydroxides: an X-ray absorption and diffraction study, Inorg. Chem., 1998, 37: 1812.CrossRefGoogle Scholar
  25. 25.
    Hu, C. W., He, Q. L., Wang, E. B., Synthesis characterization and catalysis of pillared anion clay (VI)—structure, property and oxidizing activity of Zn2Al-SiW11 and Zn2Al-SiW11Z, Prog. Natur. Sci., 1997, 7(6): 675.Google Scholar
  26. 26.
    Wang, E. B., Hu, C. W., Xu, L., Introduction of the Polyoxometalate Chemistry (in Chinese), Beijing: Chemical Industry Press, 1997, 114–118.Google Scholar
  27. 27.
    Kwon, T., Tsigdinos, G. A., Pinnavaia, T. J., Pillaring of layered double hydroxides (LDHs) by polyoxometalate anions, J. Am. Chem. Soc., 1988, 110:3653.CrossRefGoogle Scholar
  28. 28.
    Hu, C. W., He, Q. L., Wang, E. B. et al., New route of preparation of layer-pillared catalyst and its catalytic activities for the oxidation of benzaldehyde using H2O2 as oxidant, Chin. J. Mol. Catal. (in Chinese), 1996, 10(1): 67.Google Scholar
  29. 29.
    Hu, C. W., He, Q. L., Wang, E. B. et al., The catalytic activities of a new type layer-pillared clay catalyst for the esterification reaction, Chin. J. Catal. (in Chinese), 1996, 17(3): 237.Google Scholar
  30. 30.
    Xu, L., Hu, C. W., Wang, E. B., Advances in study of a new class of pillared layered microporous materials—polyoxometalatetype hydrotalcite-like catalysts, J. Natur. Gas. Chem., 1997(2): 155.Google Scholar
  31. 31.
    He, Q. L., Hu, C. W., Wang, E. B. et al., Synthesis, characterization, and reactivity of polyoxometalate anions, Chin. Sci. Bull., 1997, 42(11): 914.CrossRefGoogle Scholar
  32. 32.
    Hu, C. W., Zhang, X., Xu, L. et al., Oxidative catalysis of Keggin anion [XW11O39Z(H2O)]n-pillared clays in the reaction of acetaldehyde with H2O2, Appl. Clay. Sci., 1998(13): 495.Google Scholar
  33. 33.
    Bahranowski, K., Bueno, G., Wcislo, K. et al., Oxiditive dehydrogenation of propane over calcined vanadate-exchanged Mg, Al-layered double hydroxides, Appl. Catal., A, General, 1999, 185: 65.CrossRefGoogle Scholar
  34. 34.
    Gardner, E. A., Yun, S. K., Pinnavaia, T. J. et al., On the nature of selective olefin oxidation catalysts derived from molybdate- and tungstate-intercalated layered double hydroxides, Appl. Catal, Ser. A, 1998, 167: 65.CrossRefGoogle Scholar
  35. 35.
    Guo, Y. H., Wang, Y. H., Hu, C. W. et al., Microporous polyoxometalates POMs/SiO2: synthesis and photocatalytic degradation of aqueous organocholorine pesticides, Chem. Mater., 2000, 12(11): 3501.CrossRefGoogle Scholar
  36. 36.
    Watanabe, Y., Yamamoto, K., Tatsumi, T., Epoxidation of alkenes catalyzed by heteropolyoxometalate as pillars in layered double hydroxides, J. Mol. Catal., Ser. A, General, 1999, 145: 281.Google Scholar
  37. 37.
    Robins, D. S., Dutta, P. K., Examination of fatty acid exchanged layered double hydroxides as supports for photochemical assemblies, Langmuir, 1996, 12: 402.CrossRefGoogle Scholar

Copyright information

© Science in China Press 2001

Authors and Affiliations

  • Hu Changwen
    • 1
  • Li Danfeng
    • 1
  • Guo Yihang
    • 1
  • Wang Enbo
    • 1
  1. 1.Institute of Polyoxometalate ChemistryNortheast Normal UniversityChangchunChina

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