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Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]0.44]

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Abstract

In this paper we report the hydrothermal synthesis and characterisation of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5 [V0.32 4+V0.68 5+O2PO4P(OH)2 0.44]. The phase purity of the solid was established using powder X-ray diffraction, single crystal X-ray diffraction, TGA, DTA, FTIR, UV-Vis and magnetic susceptibility measurements. Crystal data: orthorhombic,Pnma,a = 90289,b = 8.8962 andc = 15.9813 Å,V = 1283.7Å3,Z = 8. The structure contains layers made of VO5 square pyramids and PO4 tetrahedra; adjacent layers are connected through disordered tetrahedral PO2(OH)2 units. Ethylenediammonium cations occupy cavities in between the layers.

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References

  1. Centi G, Trifiro F, Ebner J R and Franchetti V M 1998Chem. Rev. 88 55

    Article  Google Scholar 

  2. Lii K H 1992J. Chinese Chem. Soc. 39 569

    Article  CAS  Google Scholar 

  3. Roca M, Marcos M D, Amoros P, Beltran-Porter A, Edwards A J and Beltran-Porter D 1996Inorg. Chem. 35 5613

    Article  CAS  PubMed  Google Scholar 

  4. Zhang Y P, Warren C J, Clearfield A and Haushalter R C 1998Polyhedron 17 2575

    Article  CAS  Google Scholar 

  5. Ayyappan P, Ramanan A and Torardi C 1998Inorg. Chem. 37 3628

    Article  CAS  PubMed  Google Scholar 

  6. Ayyappan P, Ramanan A, Joy P A and Pring A 1999Solid State Ionics 120 233

    Article  Google Scholar 

  7. Chippindale A M and Cowley A R 1991J. Solid State Chem. 159 59

    Article  Google Scholar 

  8. Soghomonian V, Chen Q, Haushalter R C and Zubieta J 1993Angew. Chem., Int. Ed. Engl. 32 610

    Article  Google Scholar 

  9. Riou D and Ferey G 1994J. Solid State Chem. 111 422

    Article  CAS  Google Scholar 

  10. Harrison W T A, Hsu K and Jacobson A J 1995Chem. Mater. 7 2004

    Article  CAS  Google Scholar 

  11. Zhang Y, Clearfield A and Haushalter R C 1995Chem. Mater. 7 1221

    Article  CAS  Google Scholar 

  12. Lu Y, Haushalter R C and Zubieta J 1998Inorg. Chim. Acta 268 257

    Article  CAS  Google Scholar 

  13. Zhang D, Shi Z and Feng S H 2001Chem. Res. Chinese Univ. 17 249

    Article  Google Scholar 

  14. Du H B, Liao L B,Yang Z Z and Xiong M 2001Acta Chim. Sinica 59 274

    CAS  Google Scholar 

  15. Chippindale A M 2000Chem. Mater. 12 818

    Article  CAS  Google Scholar 

  16. Ayyappan P 1999Chemistry of intercalated vanadyl phosphates: Synthesis, structure and magnetic properties, Ph D thesis, Indian Institute of Technology, New Delhi

    Google Scholar 

  17. Sheldrick G M 1996 SADABS, a software for empirical absorption correction, University of Göttingen, Göttingen, Germany; SHELXTL Reference Manual, Version 5.03, Siemens Energy and Automation, Inc., Analytical Instrumentation, Madison, WI

    Google Scholar 

  18. Brown I D and Altermatt D 1985Acta Crystallogr. B41 244

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry, Indian Institute of Technology, 110 016, New Delhi, India

    P. Ayyappan, Minakshi Asnani & A. Ramanan

  2. Institut des Matériaux de Nantes, Laboratoire de Chimie des Solides, CNRS, University of Nantes, France

    Y. Piffard

Authors
  1. P. Ayyappan
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  2. Minakshi Asnani
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  3. A. Ramanan
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  4. Y. Piffard
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Correspondence to A. Ramanan.

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Ayyappan, P., Asnani, M., Ramanan, A. et al. Hydrothermal synthesis of a new ethylenediammonium intercalated vanadyl phosphate, (H3NCH2CH2NH3)0.5[V0.324+V0.685+O2PO4{P(OH)2}0.44]0.44]. J Chem Sci 115, 33–40 (2003). https://doi.org/10.1007/BF02899317

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  • DOI: https://doi.org/10.1007/BF02899317

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