Fibers and Polymers

, Volume 3, Issue 3, pp 97–102 | Cite as

Preparation and properties of waterborne poly(urethane-urea) ionomers effect of the type of neutralizing agent

  • Jung-Eun Yang
  • Young-Hee Lee
  • Young-Seok Koo
  • Young-Jin Jung
  • Han-Do Kim


A series of waterborne poly(urethane-urea) anionomers were prepared from isophorone diisocyanate (IPDI), polycaprolactone diol (PCL), dimethylol propionic acid (DMPA), ethylene diamine (EDA), and triethylamine (TEA), NaOH, or Cu(COOCH3)2 as neutralizing agent. This study was performed to decide the effect of neutralizing agent type on the particle size, viscosity, hydrogen bonding index, adhesive strength, antistaticity, antibacterial and mechanical properties. The particle size of the dispersions decreased in the following order: TEA based samples (T-sample), NaOH based samples(N-sample), and Cu(COOCH3)2 based sample (C-sample). The viscosity of the dispersions increased in the order of C-sample, N-sample, and T-sample. Metal salt based film samples (N and C-sample) had much higher antistaticity than TEA based sample. By infrared spectroscopy, it was found that the hydrogen bonding index (or fraction) of samples decreased in the order of T-sample, N-sample, and C-sample. The adhesive strength and tensile modulus/strength decreased in the order of T-sample, N-sample, and C-sample. The C-sample had strong antibacterial halo, however, T- and N-samples did not.


Waterborne Poly(urethane-urea) Ionomer Neutralizing agent Hydrogen bonding Antibacterial 


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  1. 1.
    J. A. Miller, K. K. S. Hwang, and S. L. Cooper,J. Macromol. Sci. Phys.,B22(2), 321 (1983).Google Scholar
  2. 2.
    J. T. Koberstein and R. S. Stein,J. Polym. Sci., Polym. Phys.,21, 1439 (1983).CrossRefGoogle Scholar
  3. 3.
    A. Rembaum, H. Rile, and R. Somoano,J. Polym. Sci.,138, 457 (1970).Google Scholar
  4. 4.
    A. Rembaum, S. D. S. Yen, R. F. Randal, and M. Shen,J. Macromol. Sci.,A4(3), 715 (1970).Google Scholar
  5. 5.
    H. A. Salah, K. C. Frisch, H. X. Xiao, and J. A. Mclean,J. Polym. Sci., Polym. Chem.,25, 2127 (1987).CrossRefGoogle Scholar
  6. 6.
    O. Lorenz and H. Hick,Angew. Macromol. Chem.,72, 115 (1978).CrossRefGoogle Scholar
  7. 7.
    I. Dimitrievski, T. Malavasic, U. Osdredkar, and I. Vizovisek,Vestn. Slov. Kem. Drus.,35(3), 253 (1988).Google Scholar
  8. 8.
    K. K. S. Hwang, C. Z. Yang, and S. L. Cooper,Polym. Eng. Sci.,21, 1027 (1981).CrossRefGoogle Scholar
  9. 9.
    C. Geraldine and A. Eisenberg,Ind. Eng. Chem. Prod. Res. Dev.,20, 271 (1981).CrossRefGoogle Scholar
  10. 10.
    Y. Chen and Y. L. Chen,J. Appl. Polym. Sci.,46(3), 435 (1992).CrossRefGoogle Scholar
  11. 11.
    O. Lorenz, H. J. August, H. Hick, and F. Triekes,Angew. Makromol. Chem.,63, 11 (1977).CrossRefGoogle Scholar
  12. 12.
    D. Dieterich, G. Belle, and H. Schmeiner,Ger. Offen.,2, 735 (1979).Google Scholar
  13. 13.
    D. J. Hourston, G. D. Williams, R. Satguru, J. C. Padget, and D. Pears,J. Appl. Polym. Sci.,74(3), 556 (1999).CrossRefGoogle Scholar
  14. 14.
    M. M. Coleman, D. J. Skrovanek, J. Hu, and P. C. Painter,Macromolecules,21, 59 (1988).CrossRefGoogle Scholar
  15. 15.
    T. C. Wen and M. S. Wu,Macromolecules,32, 2712 (1999).CrossRefGoogle Scholar
  16. 16.
    C. S. P. Sung and N. S. Schneider,Macromolecules,10, 452 (1977).CrossRefGoogle Scholar
  17. 17.
    S. K. Pollack, D. Y. Shen, S. L. Hsu, Q. Wang, and H. D. Stidham,Macromolecules,22, 551 (1989).CrossRefGoogle Scholar
  18. 18.
    R. W. Coleman, G. M. Ester, and S. L. Cooper,Macromolecules,3(5), 579 (1970).CrossRefGoogle Scholar

Copyright information

© The Korean Fiber Society 2002

Authors and Affiliations

  • Jung-Eun Yang
    • 1
  • Young-Hee Lee
    • 1
  • Young-Seok Koo
    • 2
    • 1
  • Young-Jin Jung
    • 3
    • 1
  • Han-Do Kim
    • 1
  1. 1.Department of Textile EngineeringPusan National UniversityPusanKorea
  2. 2.Department of Footwear EngineeringDongseo UniversityPusanKorea
  3. 3.Department of Fiber EngineeringMiryang National UniversityMiryangKorea

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