Abstract
The gold nanoparticles in diameter of 10–95 nm have been prepared by Frens procedure, all of which exhibit a resonance scattering peak at 580 nm. The mechanism of resonance scattering for gold nanoparticle has been considered according to the wave motion theory of nanoparticle in liquid. The principle of superamolecular interface energy band(SIEB) has been set up and utilized to explain the relationship between the diameter and colors for gold nanoparticle in liquid. A novel spectrophotometric ruler for the determination of the diameter has been proposed according to the relationship of the maximum absorption wavelength and diameter.
Similar content being viewed by others
References
Tang Fangqiong, Meng Xianwei, Cheng Dong et al., Glucose biosensor enhanced by nanoparticles, Science in China, Series B, 2000, 43(3): 268.
Van der Zande, B. M. I., Bohmer, M. R., Fokkinket, L. G. J. et al., Aqueous gold sols of rod-shaped particle, J. Phys. Chem. B, 1997, 101: 852.
Krug, II. J. T., Wang, G. D., Emory, S. R. et al., Efficient Raman enhancement and intermittent light emission observed in single gold nanocrystals, J. Am. Chem. Soc., 1999, 121: 9208.
Wang Fuyong, Preparation of colloidal gold probe and its applications, Foreign Medicine, Series of Clinic Biochemistry and Assay (in Chinese),1991, 12(4): 145.
Clark, B. K., Gregorg, B. W., Avila, A. et al., Surface-enhanced electronic Raman scattering from self-assembled alkanethiol monokyers on gold surface, J. Phys. Chem. B, 1999, 103: 8201.
Wang Guanghou, The stable structure and magic number of atomic clusters, Progress in Physics (in Chinese), 2000, 20: 52.
Pasternack, R. F., Collings, P. J., Gianncttd, A. et al., Resonance light scattering: A new technique for studying chromophore aggregation, J. Am. Chem. Soc., 1993, 115: 5393.
Parkash, J., Robblee, J. H., Agnew, J. et al., Depolarized resonance light scattering by porphyrin and chlorophyll an aggregates, Biophysical Journal, 1998, 74: 2089.
Liu Shaopu, Liu Zhongfang, Li Ming, The second order scattering spectroscopic study of ion associated complex and its analytical applications, Acta Chimica Sinica (in Chinese), 1995, 53: 1178.
Huang Chengzi, Li Ke’an, Tong Shengyang, Spectroscopic study of the interation of soluble cation porphyrin and nucleic acid, Chem. J. Chinese Universities (in Chinese), 1997, 18(4): 525.
Collings, P. J., Gibbs, E. J., Starr, T. E. et al., Resonance light scattering and its application in determining the size, shape, and aggregation number for supramolecular assemblies of chromophores, J. Phys. Chem. B, 1999, 103(40): 8474.
Ma Qunqi, Liu Yuqun, Li Ke’an et al., Rayleigh light scattering and its application to biochemical analysis, Chin. Sci. Bull. (in Chinese), 1999, 44(6): 682.
Jiang Zhiliang, Li Fang, Huang Shengmian et al., Study on the fluorescence system of PMo heteropoly acid-rhodamine B and its application, Analytical and Testing Technology and Instruments (in Chinese), 1999, 5(3): 157.
Liang Hong, Sheng Xincan, Jiang Zhiliang, The photochemical study of HAS and BSA with resonance scattering and fluorescence spectroscopy, Chinese Chemical Letters (in Chinese), 2000, 11: 251.
Jiang Zhiliang, Li Fang, Li Tingsheng et al., The relationship between gold nanoparticle diameter and resonance scattering intensity, Chem. J. Chinese Universities, 2000, 21: 4888.
Jiang Zhiliang, Li Fang, Liang Hong, Resonance scattering spectroscopic study of the system of PMo heteropoly acid-rhodamine S, Acta Chimica Sinica (in Chinese), 2000, 58: 1059.
Wang Liupin, Jiang Zhiliang, Resonance scattering spectroscopic study of the photochemical system of Ag(I)-benzilic acid, Analytical and Testing Technology and Instruments (in Chinese), 2000, 6(1): 25.
Wang Chongqiang, Foundemental Molecular Immunity (in Chinese), Beijing: Beijing University Press, 1999, 243.
Liu Shaopu, Liu Zhongfang, Resonant luminescence and second order scattering spectra of Se(IV)-I- crystal violet, Chem. J. Chinese Universities (in Chinese), 1996, 17: 1213.
Huang Yongyan, Jiang Zhiliang, Wang Shengmian, The second order sacttering study of the system of AsMo heteropoly acid-rhodamine B, J. Anal. Sci. (in Chinese), 2000, 16: 127.
Liu Shaopu, Liu Zhongfang, Resonant luminescence and second order scattering spectra of Hg(II)-cyanate- Vigire blue 4R system and its applications, Chem. J. Chinese Universities (in Chinese), 1996, 17: 887.
Cheng Guozheng, Xu Jingou, Wang Xiangzhi et al., Fluorescence Analytical Methods (in Chinese), Beijing: Science Press, 1990, 102.
Zhao Zaofang, Zhou Xingyao, Zhang Wuming et al., Instrumental Analysis (in Chinese), Beijing: High Education Press, 1990, 7.
Chou Gongdu, Duan Liangyun, Basic Structure Chemistry (in Chinese), Beijing: Beijing University Press, 1995, 9–10.
Pasternack, R. F., Collings, P. J., Resonance light scattering: A new technique for studying chromophore aggrogation, Science, 1995, 269: 935.
Zhang Lide, Mou Jimei, Nanomaterial Science (in Chinese), Shengyang: Liaoning Scientific and Techlogical Press, 1994, 22.
Zu Jianjun, Lin Xipin, Du Youwei et al., Nanostructure materials (in Chinese), Chinese J. Nature, 1999, 21(6): 315.
Sun Xiaoqiang, Meng Qi, Yan Haibo, Introduction of Superamolecular Chemistry (in Chinese), Beijing: China Oil and Chemical Press, 1997, 137–138.
Xie Youchang, Shao Meicheng, Structural Chemistry, Vol. 1 (in Chinese), Beijing: People’s Education Press, 1979, 158–159.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jiang, Z., Feng, Z., Li, T. et al. Resonance scattering spectroscopy of gold nanoparticle. Sc. China Ser. B-Chem. 44, 175–181 (2001). https://doi.org/10.1007/BF02879535
Issue Date:
DOI: https://doi.org/10.1007/BF02879535