Skip to main content
Log in

Phosphorus chloride-metal chloride-alkyl chloride complexes: Reactions with vanadium(III) chloride and vanadium(V) oxychloride

  • Inorganic and Analytical
  • Published:
Proceedings of the Indian Academy of Sciences - Chemical Sciences Aims and scope Submit manuscript

Abstract

The reactions of anhydrous vanadium(III) chloride and vanadium(V) oxychloride with trichloro- and phenyl dichloro-phosphine have been studied in the presence of alkylating agents such astert-butyl chloride,tert-amyl chloride, cyclohexyl chloride and triphenyl methyl chloride. Solid products have been obtained. The structures of the complexes have been assigned on the basis of elemental analyses, infrared spectra, magnetic susceptibility and conductivity data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Buchner B and Lockart L B 1951J. Am. Chem. Soc. 73 755

    Article  Google Scholar 

  • Bullock J I, Parrett F W and Taylor N J 1972J. Chem. Soc. Dalton p. 1843

  • Bullock J I, Parrett F W and Taylor N J 1973J. Chem. Soc. Dalton p. 522

  • Casey A T and Clark R J H 1968Inorg. Chem. 7 1598

    Article  CAS  Google Scholar 

  • Clark R J H 1963J. Chem. Soc. p. 1377

  • Drake J E, Verbis J E and Wood J S 1969J. Chem. Soc. A345

  • Fergusson J E, Ropper W R and Wilkins C J 1965J. Chem. Soc. p. 3715

  • Griffiths I M and Nycholls D 1971J. Chem. Soc. A 2513

    Google Scholar 

  • Kinnear A M and Perren E A 1952J. Chem. Soc. 3 437

    Google Scholar 

  • Puri D M and Saini M S 1977Indian J. Chem. A15 362

    Google Scholar 

  • Puri D M and Saini M S 1978J. Indian Natl. Sci. Acad. A44 271

    CAS  Google Scholar 

  • Puri D M and Saini M S 1979J Indian Chem. Soc. VI 30

    Google Scholar 

  • Seel F, Ballreich K and Schmutzler R 1961Chem. Ber. 94 1173

    Article  CAS  Google Scholar 

  • Selbin J and Holmes L H Jr 1962J. Inorg. Nucl. Chem. 24 1111

    Article  CAS  Google Scholar 

  • Sneh Lata, Dubey S N and Puri D M 1980J. Indian Natl. Sci. Acad. A46 374

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lata, S., Singh, S., Dubey, S.N. et al. Phosphorus chloride-metal chloride-alkyl chloride complexes: Reactions with vanadium(III) chloride and vanadium(V) oxychloride. Proc. Indian Acad. Sci. (Chem. Sci.) 90, 333–337 (1981). https://doi.org/10.1007/BF02879408

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02879408

Keywords

Navigation