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Bulletin of Alloy Phase Diagrams

, Volume 5, Issue 2, pp 117–127 | Cite as

Phase diagrams for adsorbed layers at crystal surfaces

  • J. M. Blakely
  • R. J. Lad
  • A. G. Schrott
Adsorbed Layers

Abstract

This paper provides an introduction to the rapidly expanding field of phase equilibria within adsorbed layers on crystal surfaces. The types of diagrams used to represent the stability of surface phases and their coexistence are discussed. Experimental methods employed to determine the structure, ranges of stability, and transitions of surface phases are briefly reviewed, and several examples of surface overlayer phase diagrams are presented. Comments are made on the current status of the theoretical treatment of two-dimensional transitions.

Keywords

Phase Diagram Alloy Phase Diagram Auger Electron Spectroscopy Adsorbed Atom Thermal Desorption Spectroscopy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    E.A. Guggenheim,Thermodynamics, North Holland Publishing Co., Amsterdam (1967).Google Scholar
  2. 2.
    R. Defay, I. Prigogine, A. Bellemans and D.H. Everett,Surface Tension and Adsorption, Wiley, New York (1951).Google Scholar
  3. 3.
    W.W. Mullins, inMetal Surfaces, American Society for Metals, Metals Park, OH (1963).Google Scholar
  4. 4.
    J.W. Cahn,J. Phys., 44 (supplement to No. 12), C6–199 (1982).Google Scholar
  5. 5.
    J.M. Blakely and M. Eizenberg, inChemical Physics of Solid Surfaces and Heterogeneous Catalysis, D.P. Woodruff and D.A. King, Ed., Elsevier, Amsterdam (1981).Google Scholar
  6. 6.
    L.C. Feldman, J.W. Mayer and S.T. Picraux,Materials Analysis by Ion Channeling, Academic Press, New York (1982).Google Scholar
  7. 7.
    R.F. Willis, Ed.,Vibrational Spectroscopy of Adsorbates, Springer-Verlag, Berlin (1980).Google Scholar
  8. 8.
    C. Bouldin and E.A. Stern,Phys. Rev. B, 25, 3462 (1982).CrossRefADSGoogle Scholar
  9. 9.
    M. Henzler, inElectron Spectroscopy for Surface Analysis, H. Ibach, Ed., Springer-Verlag, Berlin (1977).Google Scholar
  10. 10.
    T. Ceva and C.J. Marti,J. Phys., 39, L-221 (1978).Google Scholar
  11. 11.
    D.E. Moncton, P.W. Stephens, R.J. Birgeneau, P.M. Horn, and G.S. Brown,Phys. Rev. Lett., 46, 1533 (1981).CrossRefADSGoogle Scholar
  12. 12.
    J.K. Kjems, L. Passell, H. Taub, J.G. Dash, and A.D. Novaco,Phys. Rev. B, 13, 1446 (1976).CrossRefADSGoogle Scholar
  13. 13.
    M. Nielsen, J.P. McTague, and L. Passell, inOrdering in Two Dimensions, S.K. Sinha, Ed., Elsevier North Holland, New York, 127–163 (1980).Google Scholar
  14. 14.
    P.W. Palmberg,J. Vac. Sci. Technol., 13, 214 (1976).CrossRefADSGoogle Scholar
  15. 15.
    B. Feuerbacher and B. Fitton, inElectron Spectroscopy for Surface Analysis, H. Ibach, Ed., Springer-Verlag, Berlin (1977).Google Scholar
  16. 16.
    P.T. Dawson and P.C. Walker inExperimental Methods in Catalytic Research, Vol.III, R.B. Anderson, Ed., Academic Press, New York (1976).Google Scholar
  17. 17.
    A. Benninghoven, C.A. Evans, Jr., R.A. Powell, R. Shimizu, and H.A. Storms, Ed.,Secondary Ion Mass Spectroscopy SIMS II, Springer-Verlag, Berlin (1979).Google Scholar
  18. 18.
    L.D. Roelofs, A.R. Kortan, T.L. Einstein, and R.L. Park,J. Vac. Sci. Technol., 18, 492 (1981).CrossRefADSGoogle Scholar
  19. 19.
    J. Suzanne, P. Coulomb and M. Bienfait,Surf. Sci., 40, 414 (1973).CrossRefADSGoogle Scholar
  20. 20.
    M. Kostelitz and J. Oudar,Surf. Sci., 27, 176 (1971).CrossRefADSGoogle Scholar
  21. 21.
    M. Eizenberg and J.M. Blakely,J. Chem. Phys., 71, 3467 (1979).CrossRefADSGoogle Scholar
  22. 22.
    J.C. Tracy and P.W. Palmberg,J. Chem. Phys., 51, 4852 (1969); J.C. Tracy and P.W. Palmberg,Surf. Sci., 14, 274 (1969).CrossRefADSGoogle Scholar
  23. 23.
    E.A. Wood,J. Appl. Phys., 35, 1306 (1963).CrossRefADSGoogle Scholar
  24. 24.
    O.E. Vilches, inOrdering in Two Dimensions, S.K. Sinha, Ed., Elsevier North Holland, New York, 25–28 (1980).Google Scholar
  25. 25.
    J.G. Dash and J. Ruvalds, Ed.,Phase Transitions in Surface Films, Plenum, New York (1980).Google Scholar
  26. 26.
    S. Ostlund and A.N. Berker,Phys. Rev. Lett., 42, 843 (1979).CrossRefADSGoogle Scholar
  27. 27.
    S.K. Sinha, Ed.,Ordering in Two Dimensions, Elsevier North Holland, New York (1980).Google Scholar
  28. 28.
    A. Thomy and X. Duval,J. Chim. Phys., 66, 1966 (1969);67, 286 (1970);67, 1101 (1970).Google Scholar
  29. 29.
    J.A. Venables, H.M. Kramer and G.L. Price,Surf. Sci., 55, 373 (1976);57, 782 (1976).CrossRefADSGoogle Scholar
  30. 30.
    D.M. Butler, J.A. Litzinger, and G.A. Stewart,Phys. Rev. Lett., 44, 466 (1980).CrossRefADSGoogle Scholar
  31. 31.
    M.D. Chinn and S.C. Fain, Jr.,Phys. Rev. Lett., 39, 146 (1977).CrossRefADSGoogle Scholar
  32. 32.
    C. Marti, B. Croset, P. Thorel, and J.P. Coulomb,Surf. Sci., 65, 532 (1977).CrossRefADSGoogle Scholar
  33. 33.
    R.J. Birgeneau, E.M. Hammons, P. Heiney, and P.W. Stephens, inOrdering in Two Dimensions, S.K. Sinha, Ed., Elsevier North Holland, New York, 29–38 (1980).Google Scholar
  34. 34.
    L.D. Roelofs and P.J. Estrup,Surf. Sci., 125, 51 (1983).CrossRefADSGoogle Scholar
  35. 35.
    R. Imbihl, R.J. Behm, K. Christmann, G. Ertl, and T. Matsushima,Surf. Sci., 117, 257 (1982).CrossRefADSGoogle Scholar
  36. 36.
    W. Kinzel, W. Selke, and K. Binder,Surf. Sci., 121, 13 (1982).CrossRefADSGoogle Scholar
  37. 37.
    M.G. Lagally, T.M. Lu, and G.C. Wang, inOrdering in Two Dimensions, S.K. Sinha, Ed., Elsevier North Holland, New York, 113–121 (1980).Google Scholar
  38. 38.
    A.R. Kortan and R.L. Park,Phys. Rev. B, 23, 6340 (1981).CrossRefADSGoogle Scholar
  39. 39.
    T.L. Einstein, inChemistry and Physics of Solid Surfaces, Vol. IV, R. Vanselow and R. Howe, Ed., Springer-Verlag, New York (1982).Google Scholar
  40. 40.
    M.K. Debe and D.A. King,J. Phys. C, 10, L303 (1977); T.E. Felter, R.A. Barker, and P.J. Estrup,Phys. Rev. Lett., 38, 1138 (1977).CrossRefADSGoogle Scholar
  41. 41.
    R.A. Barker and P.J. Estrup,Phys. Rev. Lett., 41, 1307 (1978).CrossRefADSGoogle Scholar
  42. 42.
    I. Stensgaard, L.C. Feldman, and P.J. Silverman,Phys. Rev. Lett., 42, 247 (1979); L.C. Feldman, P.J. Silverman, and I. Stensgaard,Surf. Sci., 87, 410 (1979).CrossRefADSGoogle Scholar
  43. 43.
    R.A. Barker and P.J. Estrup,J. Chem. Phys., 74, 1442 (1981).CrossRefADSGoogle Scholar
  44. 44.
    M.R. Barnes and R.F. Willis,Phys. Rev. Lett., 41, 1729 (1978).CrossRefADSGoogle Scholar
  45. 45.
    L. Onsager,Phys. Rev., 65, 117 (1944).MATHCrossRefADSMathSciNetGoogle Scholar
  46. 46.
    M.E. Fisher,Rev. Mod. Phys., 46, 597 (1974).CrossRefADSGoogle Scholar
  47. 47.
    T.L. Hill,Statistical Mechanics, McGraw-Hill, New York (1956).MATHGoogle Scholar
  48. 48.
    L.P. Kadanoff, inProc. Int. School Phys. Enrico Fermi, M.S. Green, Ed., Academic Press, New York (1971).Google Scholar
  49. 49.
    L.P. Kadanoff, W. Gotze, D. Hamblen, R. Hecht, E.A.S. Lewis, V.V. Palciauskas, M. Rayl, J. Swift, D. Aspnes, and J. Kane,Rev. Mod. Phys., 39, 395 (1967).CrossRefADSGoogle Scholar
  50. 50.
    C. Domb and M.S. Green, Ed.,Phase Transitions and Critical Phenomena, Academic Press, New York (1974).Google Scholar
  51. 51.
    L.D. Roelofs, inChemistry and Physics of Solid Surfaces, Vol. IV, R. Vanselow and R. Howe, Ed., Springer-Verlag, New York (1982).Google Scholar
  52. 52.
    K.G. Wilson and J. Kogut,Phys. Rpt., 12C, 75 (1974).CrossRefADSGoogle Scholar
  53. 53.
    A.N. Berker, S. Ostlund, and F.A. Putnam,Phys. Rev. B, 17, 3650 (1978).CrossRefADSGoogle Scholar
  54. 54.
    R.G. Caflisch and A.N. Berker,Phys. Rev. B, 29, 1279 (1984).CrossRefADSGoogle Scholar

Copyright information

© Springer 1984

Authors and Affiliations

  • J. M. Blakely
    • 1
  • R. J. Lad
    • 1
  • A. G. Schrott
    • 1
  1. 1.Materials Science and Engineering Cornell UniversityIthaca

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