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Pulse radiolysis of some aromatic sulphoxides in aqueous solutions

  • K Kishore
  • G R Dey
  • P N Moorthy
Physical and Theoretical
  • 11 Downloads

Abstract

Reactions ofe aq and H-atoms with aromatic sulphoxides such as dibenzyl, diphenyl and di-4-chlorophenyl sulphoxides have been studied at various pH values and the spectral and kinetic properties of the transients determined.e aq addition to dibenzyl sulphoxide was found to lead to the scission of the C−S bond giving benzyl radicals, but such bond breakage was not observed in other cases.

Keywords

Pulse radiolysis aromatic sulphoxides transients 

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References

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Copyright information

©  0144 V 2 1993

Authors and Affiliations

  • K Kishore
    • 1
  • G R Dey
    • 1
  • P N Moorthy
    • 1
  1. 1.Applied Chemistry DivisionBhabha Atomic Research CentreBombayIndia

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