Transimination and reduction of imines usingnadh models
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Schiff bases prepared from aromatic aldehydes and alicyclic amines undergo transimination and reduction with 3,5-dicarboethoxy-2,6-dimethyl-1,4-dihydropyridine, as thenadh model in the presence of aromatic amines in acetic acid. This sequence of steps is analogous to a similar chemical mechanism proposed for glutamate dehydrogenase. In the absence of thenadh model, only the transimination process is observed.
KeywordsTransimination nadh models imines 1,4-dihydropyridines glutamate dehydrogenase N-arylideneanilines N-benzylaniline N-benzylidenecyclohexylamine
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