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Transimination and reduction of imines usingnadh models

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Abstract

Schiff bases prepared from aromatic aldehydes and alicyclic amines undergo transimination and reduction with 3,5-dicarboethoxy-2,6-dimethyl-1,4-dihydropyridine, as thenadh model in the presence of aromatic amines in acetic acid. This sequence of steps is analogous to a similar chemical mechanism proposed for glutamate dehydrogenase. In the absence of thenadh model, only the transimination process is observed.

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References

  • Enzyme nomenclature (Amsterdam: Elsevier) 1965 p. 76

  • Lowe J N and Ingraham L L 1974An introduction to biochemical reactions, (New Jersey: Prentice Hall) Ch. 3, p. 99

    Google Scholar 

  • Singh S, Trehan A K and Sharma V K 1978Tetrahedron Lett. 5029

  • Singh S and Sharma V K 1979Tetrahedron Lett. 2733

  • Singh S, Chinna S, Sharma V K and Sachdev S S 1982J. Chem. Soc. Chem. Commun. 453

  • Smith E L, Austen B H, Blumenthal and Nyc J F 1975The Enzymes, (ed.) P D Boyer. (New York: Academic Press) Vol. 11, 357

    Google Scholar 

  • Snell E E and DiMari S J 1970The enzymes, (ed.) P D Boyer (New York: Academic Press) Vol. 2, p. 335

    Google Scholar 

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Singh, S., Gill, S. & Singh, I. Transimination and reduction of imines usingnadh models. Proc. Indian Acad. Sci. (Chem. Sci.) 93, 1179–1183 (1984). https://doi.org/10.1007/BF02863622

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  • DOI: https://doi.org/10.1007/BF02863622

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