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Wuhan University Journal of Natural Sciences

, Volume 6, Issue 4, pp 854–858 | Cite as

Study on the reaction mechanism of naphthalene with oxalyl chloride

  • Wu Lin
  • Qin Yi-min
  • Huang Bo
  • Zong Zhi-ming
  • Wei Xian-yong
  • Chen Qing-ru
  • Zou Guo-lin
Article

Abstract

The reaction of naphthalene with oxalyl chloride in the presence of anhydrous AlCl3 was investigated. The homolog of dinaphthyl methanone can be obtained mainly from this reaction. Naphthalene conversion does not have evident correlation with the amount of AlCl3. The results show that the reaction proceeds via carbon cation electrophilic substitution reaction-free radical substitution reaction pathway.

Key words

naphthalene oxalyl chloride carboncation free radical reaction mechanism 

CLC number

O 621 

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Copyright information

© Springer 2001

Authors and Affiliations

  • Wu Lin
    • 1
  • Qin Yi-min
    • 1
  • Huang Bo
    • 1
  • Zong Zhi-ming
    • 2
  • Wei Xian-yong
    • 2
  • Chen Qing-ru
    • 2
  • Zou Guo-lin
    • 1
  1. 1.College of Life SciencesWuhan UniversityWuhanChina
  2. 2.College of Chemical EngineeringChina University of Mining & TechnologyXuzhouChina

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