Abstract
Experimental infrared and Raman data for molecular rotations in dense phases often lie in between the results predicted by theJ- andM-diffusion models of Gordon. In this paper, we present a theory which is similar in its basic approach to Gordon’s extended diffusion models (EDM) but in which the restrictions of theJ andM limits are removed. The outcome is a scheme which allows one to describe situations which fall between the two extreme pictures of theJ andM models. Application of this scheme to experiments is discussed.
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Dattagupta, S., Sood, A.K. Model for infrared and Raman studies of molecular rotations in liquids and gases. Pramana - J Phys 13, 423–445 (1979). https://doi.org/10.1007/BF02846139
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DOI: https://doi.org/10.1007/BF02846139