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Pramana

, Volume 27, Issue 5, pp 695–700 | Cite as

Relative photodissociation cross-section of NaCs molecule, using argon ion laser lines

  • A Sharma
  • M N Dixit
  • G L Bhale
Molecular Physics
  • 28 Downloads

Abstract

Laser-induced photodissociation of NaCs molecule has been observed when a mixture of Na and Cs metal vapour in a glass cell was irradiated by most of the lines of an argon ion laser. The photodissociation results in the 3P state of Na atoms which is correlated with theF 1Σ+ and G1π molecular states of NaCs. Distribution of photofragments over fine structure components 32 P 3/2 and 32 P 1/2 of Na has been studied. The ratio of intensity ofD 2 line (5890 Å) toD 1 line (5896 Å) of Na varies from around 2 at 5145 Å to about 3.5 at 4579 Å. The relative photodissociation cross-section increases monotonically as the wave-length of laser light decreases from 5145 Å to 4579 Å. It is seen that the 4579 Å photon is about 200 times more effective than the 5145 Å photon in causing the photoreaction NaCs + (Ar+ photon) → Na*(3P) + Cs(6S).

Keywords

NaCs photodissociation argon ion laser 

PACS No.

33.80 

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Copyright information

© Indian Academy of Sciences 1986

Authors and Affiliations

  • A Sharma
    • 1
  • M N Dixit
    • 1
  • G L Bhale
    • 1
  1. 1.Spectroscopy DivisionBhabha Atomic Research CentreTrombay, BombayIndia

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