Abstract
Co(HMAT)2Cl and Co(HMAT)2 base H have been synthesized and characterized by elemental analyses, magnetic moments, electronic and infrared spectral measurements. The results show them to be low spin octahedral in nature. Various parameters have been calculated using ligand field theory of spin-allowed transitions.
Similar content being viewed by others
References
Ablov A V and Gerbeleu N V 1964Russ. J. Inorg. Chem. 9 1260
Ablov A V and Gerbeleu N V 1965Russ. J. Inorg. Chem. 10 624
Ablov A V and Gerbeleu N V 1971Zh. Neorg. Khim. 16 172
Ballhausen C J and Maffitt W 1956J. Inorg. Nucl. Chem. 3 178
Beecroft B, Campbell M J M and Grazeskowiak R 1974J. Inorg. Nucl. Chem. 36 55
Campbell M J M and Grazeskowiak R 1967J. Chem. Soc. A396
Cavalca L, Nardelli M and Pava G 1962Acta Crystallogr. 15 1139
Dunlop J H and Gillard R D 1963Mol. Phys. 7 493
Dey K and De R L 1975J. Inorg. Nucl. Chem. 37 843
Geary W J 1971Coord. Chem. Rev. 7 172
Gingras B A, Somorjai R L and Bayley C H 1961Can. J. Chem. 39 973
Kuroda K and Gentile P S 1965J. Inorg. Nucl. Chem. 27 155
Legg J I and Cooke D W 1965Inorg. Chem. 4 1576
Lever A B P 1968Inorganic electronic spectroscopy p. 306
Patel M C, Shah J R and Patel R P 1973J. Indian Chem. Soc. 50 560
Poddar S N and Sana Nityananda 1975J. Indian Chem. Soc. 52 57
Pradhan B and Ramanarao D V 1977J. Indian Chem. Soc. 54 136
Rana V B, Jain P C, Swami M P and Srivastava A K 1975J. Inorg. Nucl. Chem. 37 1826
Sahani S K, Gupta S P, Sangal S K and Rana V B 1977J. Indian Chem. Soc. 9 200
Vogel A I 1958Elementary organic chemistry Part 3:Quantitative organic analysis (Longmans Green and Co.) p. 660
Wentworth R A and Piper T S 1965Inorg. Chem. 4 709
Wiles D M and Suprunchuk T 1969Can. J. Chem. 47 1087
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Patil, M.S., Shah, J.R. Possible existence of the (nitrogen base H)+ cations with cobalt(III) chelates of 2-hydroxy-5-methyl acetophenone thiosemicarbazone. Proc. Indian Acad. Sci. (Chem. Sci.) 90, 147–151 (1981). https://doi.org/10.1007/BF02843426
Issue Date:
DOI: https://doi.org/10.1007/BF02843426