Possible existence of the (nitrogen base H)+ cations with cobalt(III) chelates of 2-hydroxy-5-methyl acetophenone thiosemicarbazone
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Co(HMAT)2Cl and Co(HMAT)2 base H have been synthesized and characterized by elemental analyses, magnetic moments, electronic and infrared spectral measurements. The results show them to be low spin octahedral in nature. Various parameters have been calculated using ligand field theory of spin-allowed transitions.
Keywords2-hydroxy acetophenone thiosemicarbazone ammonia pyridine aniline, ligand field parameters
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