Synthesis of novel polymer-bonded water-soluble metal porphyrins
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The reaction of 5, 10, 15, 20-tetra-(4-pyridyl) porphyrin 1 with triruthenium dodecacarbonyl [Ru3(CO)12], zinc(II) acetate, copper(II) acetate, cobalt(II) acetate afforded complexes 2a−2d respectively. Treatment of 2a−2d with Merrifield’s peptide resin obtained 3a−3d. The compounds 3a−3d reacted with methyl iodide respectively gave 4a−4d. New complexes 4a−4d have been identified by IR, UV-visible spectra, and AES.
Key wordspolymer-bonded metal porphyrin water-soluble porphyrin synthesis
CLC numberO 627. 8
- Xiao Y X, You J S, Lan Z W,et al. Study on synthesis of polymer-supported Manganese (III) porphyrins and catalyzed olefin epoxidation [J].Chemical Research and Application, 1996,8(3): 376–380 (Ch).Google Scholar
- Li Z Y, Li C, Liang J L,et al. Synthesis of polymer-bonded ruthenium (II) and osmium (II) porphyrins [J].Journal of Wuhan University (Natural Science Edition), 1998,44(6): 676–678 (Ch).Google Scholar