Abstract
Manganese(II) complexes of the general composition, Mn(L)2X2 (X = Cl or 1/2 SO4,L = semicarbazones and thiosemicarbazones of acetone, ethyl methyl ketone and 2-methyl cyclohexanone) have been prepared and characterised by elemental analysis, magnetic moments, conductance measurements, IR, electronic and ESR spectral studies. All the complexes are six-coordinate octahedral.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Burns G R 1968Inorg. Chem. 7 277
Campbell M J and Grazeskowiak R 1968J. Inorg. Nucl. Chem. 30 1865
Campbell M J, Grazeskowiak R and Thomas R 1976Spectrochim. Acta A32 556
Chandra S, Pandeya K B, Sindhwani S K and Singh R P 1980Gazz. Chim. Italia 110 207
Dyer J R 1974Application of absorption spectroscopy of organic compounds (New Delhi: Prentice Hall) p. 40
Eskenzari R, Raskovan J and Levitus R 1966J. Inorg. Nucl. Chem. 28 521
Figgis B N and Lewis J 1964Prog. Inorg. Chem. 6 37
Gerzy W G 1971Coord. Chem. Rev. 8 81
Heidt C J M, Koster G F and Johnson A N 1958J. Am. Chem. Soc. 30 6471
Levanon H 1968Z. Luz. J. Chem. Phys. 49 2031
Mashima M 1964Bull. Chem. Soc. Jpn 37 974
McGravely B R 1966Transition metal chemistry Vol 3 (ed.) R L Carlin (New York: Marcell Dekker) p. 169
Orgal L E 1955J. Chem. Phys. 23 1004
Pradhan B R and Raman D V J 1974J. Indian Chem. Soc. 54 136
Preti C and Tosi G 1976Aust. J. Chem. 20 543
Rana V B, Jain P C, Swami M P and Srivastava A K 1975J. Inorg. Nucl. Chem. 37 1826
Reed G and Cohn M 1970J. Biol. Chem. 255 662
Sterk H and Ziegler E 1966Monatsh Chem. 97 1131
Wiles D M, Gingras B A and Suprunchuk T 1967Can. J. Chem. 45 471
Wiles D M and Suprunchuk T 1969Can. J. Chem. 47 1087
Yamagushi A, Penland R B, Mizushima S, Lane T J, Curran C and Quagliano J V 1958J. Am. Chem. Soc. 80 527
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Chandra, S., Kumar, Y. Manganese (II) complexes of some nitrogen-oxygen and nitrogen-sulphur donor ligands. Proc. Indian Acad. Sci. (Chem. Sci.) 92, 249–255 (1983). https://doi.org/10.1007/BF02841242
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02841242