Abstract
Excess enthalpies (H E) for mixtures of cyclohexanone with propan-1-ol. propan-2-ol, butan-1-ol, butan-2-ol and 2-methyl propan-1-ol at 298.15 K have been measured over the entire composition range. All mixed endothermically with the maximum values ofH E occurring at equimole fraction. Comments about the molecular interactions contributing to the excess enthalpies of a cyclic ketone + an alcohol are made on the basis of these results.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Neumann S and Weber U V 1963J. Prakt. Chem. 19 206
Rao M V P and Naidu P R 1976J. Chem. Thermodyn. 8 96
Riddick J A and Bunger W B 1970Organic solvents 3rd edn. (New York: Interscience) vol. 2
Shanmugasundaram V and Mohan R 1980Bull. Soc. Chim. Belg. 89 409
Shanmugasundaram V and Mohan R 1982Bull. Soc. Chim. Belg. 91 885
Shanmugasundaram V and Mohan R 1983J. Indian Chem. Soc. 60 298
Stokes R H and Marsh K N 1972Annu. Rev. Phys. Chem. 23 65
Timmermans J 1965Physico-chemical constants of pure organic compounds (Amsterdam: Elsevier) vol. 1
Waclawck Witold 1978Bull. Acad. Pol. Sci., Ser. Sci. Chim. 26 135
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Krishnaiah, A., Surendranath, K.N. & Ramakrishna, M. Excess enthalpies for mixtures of cyclohexanone with isomeric propanols and butanols at 298.15 K. Proc. Indian Acad. Sci. (Chem. Sci.) 100, 323–328 (1988). https://doi.org/10.1007/BF02840542
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF02840542