Abstract
A simple, but general model which enables prediction of the electronic structure adopted by ad n ion in an axially distorted octahedron of ligands (D 4h) is described. The variousd n configurations (n = 1 to 9) are briefly reviewed with some recent results concerning the stabilization of unusual electronic configurations or oxidation states in oxides.
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Buffat, B., Demazeau, G., Pouchard, M. et al. A simple model for predicting the electronic configuration of a dn ion in a tetragonally distorted octahedral environment. Proc. Indian Acad. Sci. (Chem. Sci.) 93, 313–320 (1984). https://doi.org/10.1007/BF02840522
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DOI: https://doi.org/10.1007/BF02840522