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A simple model for predicting the electronic configuration of a dn ion in a tetragonally distorted octahedral environment

  • Bernard Buffat
  • Gérard Demazeau
  • Michel Pouchard
  • Paul Hagenmuller
Solid Statet Chemistry and Surface Chemistry
  • 42 Downloads

Abstract

A simple, but general model which enables prediction of the electronic structure adopted by ad n ion in an axially distorted octahedron of ligands (D 4h) is described. The variousd n configurations (n = 1 to 9) are briefly reviewed with some recent results concerning the stabilization of unusual electronic configurations or oxidation states in oxides.

Keywords Electronic configuration octahedral environment 

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Copyright information

© Indian Academy of Sciences 1984

Authors and Affiliations

  • Bernard Buffat
    • 1
  • Gérard Demazeau
    • 1
  • Michel Pouchard
    • 1
  • Paul Hagenmuller
    • 1
  1. 1.Laboratoire de Chimie du Solide du CNRSTalence CedexFrance

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