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Ruthenium(III) catalyzed oxidation of 1-phenylethanol and substituted 1-phenylethanols by phenyliodosoacetate

  • K. Vijayasri
  • J. Rajaram
  • J. C. Kuriacose
Inorganic and Analytical
  • 24 Downloads

Abstract

Ruthenium(III) catalysed oxidation of 1-phenylethanol and substituted 1-phenylethanols by phenyliodosoacetate (pia) in acetic acid is studied and a probable mechanism suggested. The proposed mechanism involves the formation of a complex of Ru(III) and (pia) which reacts with the substrate, S, in a slow step. Spectrophotometric evidence for this complex is presented. Studies on the effect of substituents suggest a transition state involving a π-complex.

Keywords

Oxidation 1-phenylethanol Ru(III) catalyst phenyliodosoacetate 

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Copyright information

© Indian Academy of Sciences 1985

Authors and Affiliations

  • K. Vijayasri
    • 1
  • J. Rajaram
    • 1
  • J. C. Kuriacose
    • 1
  1. 1.Department of ChemistryIndian Institute of TechnologyMadrasIndia

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