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Wuhan University Journal of Natural Sciences

, Volume 10, Issue 2, pp 460–464 | Cite as

Hemoglobin biocatalyst polymerization of aniline by UV-vis spectraphotometry

  • Hu Xing
  • Chen Dong-ming
  • Zou Guo-lin
Article

Abstract

A biocatalytic route for the synthesis of a water soluble and conducting complex of polyaniline (PANI)/sodium dodecylsulfate (SDS) is presented. Hemoglobin is used in SDS anion surfactant. The polymerization proceeded quickly to result in a homogeneous emeraldine-colored dispersion of PANI. Absorption spectra of PANI/SDS in the aqueous dispersions at various pH values confirms that the reversibility of dedoping and redoping process of PANI/SDS and shows that the transition from emeraldine salt to emeraldine base form occurred at about pH 10.0–11.0 in this anionic micellar system. PANI/SDS in the organic solutions dedoped initially and redoped after 24 h.

Key words

hemoglobin biocatalysis polyaniline dedoping redoping 

CLC number

Q 554+. 6 Q 811. 2 

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Copyright information

© Springer 2005

Authors and Affiliations

  1. 1.College of Life SciencesWuhan UniversityWuhan, HubeiChina
  2. 2.Department of BiologyCollege of HuaihuaHuaihua, HumanChina

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