Conclusions
Coefficients that characterize the relative compression of the substance in the CJ plane and on the shock front of the detonation wave are found by means of Eqs. (8).
For a specific explosive, the state of the substance on the shock front of the detonation wave depends on the initial density (specific volume) of the charge of explosive and obeys adiabatic law (27) with adiabatic exponent (26).
Accordingly, the differences between individual explosives of the CaHbOcNd type with respect to detonation velocity (36), mass velocity (38) and (39), and pressure (40) and (41) in the CJ plane and on the shock front of the detonation wave are determined mainly by the density of the single crystal of the corresponding explosive and its detonative heat of explosion.
For individual explosives of the given type, detonative heat of explosion reaches its maximum at the maximum density of the charge (the maximum density of the single crystal). The corresponding values for ten explosives are shown in Table 1. A decrease in charge density is accompanied by a decrease in heat of explosion in accordance with law (37) and an increase in the importance of the thermal effect of the deflagration reactions, which are highly sensitive to the blasting conditions.
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References
F. A. Baum, L. P. Orlenko, et al., Physics of Explosion [in Russian], Nauka, Moscow (1975).
A. Ya. Apin, A. F. Belyaev, and G. S. Sosnova, “Preliminary data on the heat of explosion of mixtures of hexogen with ammonium nitrate,” in: Physics of Explosion. Report No. 3. “Experimental Scientific Research in the Physics of Explosion,” [in Russian], Izd. AN SSSR, Moscow (1955).
Yu. A. Lebedev, G. G. Lipakin, V. I. Pepekin, and A. Ya. Apin, “Thermochemical investigation of individual explosives and their mixtures,” in: Blasting [in Russian], No. 52/9, GNTI (State Scientific and Technical Publishing House), Moscow (1963).
A. Ya. Apin and Yu. A. Lebedev, “Explosive decomposition of hexogen,” Dokl. Akad. Nauk SSSR,114, No. 4. (1957).
A. Ya. Apin, N. F. Velina, and Yu. A. Lebedev, “Complete use of the energy of an explosion,” Prikl. Mekh. Tekh. Fiz., No. 5 (1976)
V. I. Vashchenko, Yu. N. Matyushin, V. I. Pepekin, and A. Ya. Apin, “Energy from the explosion of water-filled hexogen,” Fiz. Goreniya Vzryva,7, No. 3 (1971).
P. A. Paramonov, “Study of a method of testing explosives in a bulk shell of quartz sand to detect the formation of toxic gases,” in: Commercial Explosives. Blasting. Symposium No. 52/9 (1963).
L. T. Eremenko, D. A. Nesterenko, G. V. Strukov, and V. A. Garanin, “Relationship between the relative impulse of an explosion and the chemical composition of the explosive,” in: Chemical Physics of Combustion and Explosion [in Russian], Izd. RIO OIKhF AN SSSR, Chernogolovka (1977).
K. K. Andreev and A. F. Belyaev, Theory of Detonation of Explosives [in Russian], Oborongiz, Moscow (1960).
M. A. Budnikov, N. A. Levkovich, I. V. Bystrov, et al., Explosives and Blasting Powders [in Russian], Gos. Izd-vo Oboron. Prom-ti, Moscow (1958).
Z. G. Pozdnyakov and B. D. Rossi, Handbook of Commercial Explosives and Blasting Equipment [in Russian], Nedra, Moscow (1977).
S. V. Muchnik, “Principles of the turbo-explosion of explosive charges. Part 1. Toward a theory of detonation processes,” Fiz.-Tekh. Probl. Razrab. Polezn. Iskop. No. 3 (1998).
A. N. Afanasenkov, V. N. Bogomolov, and L. M. Voskoboinikov, Fiz. Goreniya Vzryva,6, No. 2 (1970).
A. Ya. Apin and N. M. Voskoboinikov, “Calculation of the parameters of the detonation wave of condensed explosives,” Prikl. Mekh. Tekh. Fiz., No. 4 (1960).
I. N. Aizenshtadt, “Method of calculating the ideal detonation velocity of condensed explosives,” Fiz. Goreniya Vzryva,12, No. 5 (1976).
A. Ya. Apin and N. F. Velina, “Critical diameters of explosive charges and the detonation velocity of hexogen,” in: Blasting. Symposium No. 63/20 (1967).
W. Baker, P. Cox, P. Westin, J. Coulesh, and R. Strelaw, Explosions. Estimates and After-Effects [Russian Translation], Vol. 1, Mir, Moscow (1986).
A. N. Dremin and K. K. Shvedov, “Determination of the Chapman-Jouguet pressure and reaction time in the detonation wave of powerful explosives,” Prikl. Mekh. Tekh. Fiz., No. 2 (1964).
A. N. Dremin, S. D. Savrov, V. S. Trofimov, and K. K. Shvedov, Detonation Waves in Condensed Media [in Russian], Moscow (1970).
M. A. Cook, The Science of Commercial Explosives [Russian translation], Nauka, Moscow (1980).
M. J. Kamlet and H. Hurwitz, “Chemistry of detonation. 4 Evaluation of a simple predictional method for detonation velocities of C-H-N-O explosives,” J. Chem. Phys.48, No. 8 (1968)
V. I. Pepekin and Yu. A. Lebedev, “Criteria for evaluating the detonation parameters of explosive,” Dokl. Akad. Nauk SSSR,234, No. 6 (1977).
L. C. Smith, “On brisance, and a plate denting test for the estimate of detonation pressure,” Explosivstoffe,15, No. 5 (1967).
L. N. Stesik and L. N. Akimova, “Dependence of detonation velocity on the initial density of the charge,” In: Physics of Explosion, Symposium No. 5 [in Russian], Izd. AN SSSR, Moscow (1956).
L. V. Dubnov, N. S. Bakharevich, and A. N. Romanov, Commercial Explosives [in Russian], Nauka, Moscow (1988).
L. V. Al'tshuler et al., “Experimental study of states in chemical reaction zone of a detonation wave,” in: Chemical Physics of Combustion and Explosion. Detonation [in Russian], Izd. IKhF AN SSSR, Chernogolovka (1980).
V. K. Bobolev, “Dependence of detonation velocity on charge diameter and detonation velocity near the limit.” in: Physics of Explosion. Symposium No. 2 [in Russian], Izd. AN SSSR, Moscow (1953).
K. K. Shvedov and A. N. Dremin, “Study of nonideal regimes of detonation of condensed explosives,” in: Improvement of Commercia Explosives. Blasting. Symposium No. 60/17 [in Russian], Nedra, Moscow (1966).
G. P. Demidyuk, “Methods of evaluating the explosion properties of simple explosives,” in: Granulated and Water-Bearing Explosives Blasting. Symposium No. 74/31 [in Russian], Nedra, Moscow (1974).
A. N. Dremin and P. F. Pokhil, “Width of the chemical reaction zone of the detonation wave of trotyl,” Dokl. Akad. Nauk SSSR,127, No. 6 (1959).
A. N. Dremin and P. F. Pokhil, “Study of the chemical reaction zone of trotyl,” Zh. Fiz. Khim., 34, No. 11 (1960).
A. N. Dremin, K. K. Shvedov, and V. A. Veretennikov, “Study of the detonation of ammonite 6ZhV and certain other explosives,” in: Commercial Explosives. Blasting. Symposium No. 52/9 [in Russian], GNTI po Gornomy Delu (State Scientific and Technical Publishing House for Mining), Moscow (1963).
V. N. Zaitsev, P. F. Pokhil, and K. K. Shvedov, “Measurement of the speed of sound in detonation products,” Dokl. Akad. Nauk SSSR,133, No. 1 (1960).
B. Ya. Svetlov and N. E. Yaremenko, Theory and Properties of Commercial Explosives [in Russian], Nedra, Moscow (1973).
G. G. Rempel, “Determination of shock-wave velocities necessary to excite the detonation of an explosive,” in: Theory of Explosives, K. K. Andreev (ed.), Oborongiz Moscow (1963).
J. Taylor, Detonation in Condensed Explosives, Clarendon Press, Oxford (1952).
V. A. Veretennikov, A. N. Dremin and K. K. Shvedov, “Determination of the detonation parameters of condensed explosives,” Fiz. Goreniya Vzryva, No. 3 (1965).
W. B. Cybulski, W. Payman, and D. W. Woodhead, “Explosion waves and shock waves. 7. The velocity of detonation in cast TNT,” Proc. R. Soc. A,197, No. 1048.
V. A. Vasil'ev and L. I. Al'bov, “Structure of the detonation wave in ammonite 6ZhV,” Fiz. Goreniya Vzryva,12, No. 2 (1976).
I. M. Voskoboinikov, “Decomposition of explosives in detonation and shock waves,” Author's Abstract of Dissertation. RIO IKhF, Moscow (1971).
A. S. Derzhavets, Z. F. Zarubina, and B. I. Shekhter, “Detonation characteristics of thermally stable explosives,” in: Improving Commercial Explosives and Methods of Using Them Blasting. Symposium No. 80/37 [in Russian], Nedra, Moscow (1978).
C. I. Mader, Numerical Modeling of Detonation, University of Calif. Press (1979).
S. D. Viktorov, N. V. Mel'nikov, G. P. Demidyuk, and L. G. Bolkhovitinov, Procedural Instructions on Calculation of the Properties of Commercial Explosives [in Russian] IFZ, Moscow (1977)
L. N. Stesik and N. S. Shvedova, “Detonation of condensed explosives with low charge densities,” Prikl. Mekh. Tekh. Fiz., No. 4 (1964).
M. M. Boiko, V. N. Kramarenko, and V. S. Solov'ev, “Features of the detonation of low-density explosives with open porosity,” in: Chemical Physics of Combustion and Explosion. Detonation [in Russian], RIO OIKhF, Chernogolovka (1977).
J. Johanson and P. Pearson, Detonation of Explosives [Russian translation], Mir, Moscow (1973).
A. I. Aniskin and K. K. Shvedov, “Effect of aluminum and manganese on detonation characteristics in mixtures with hexogen,” in: Detonation. Critical Phenomena. Physicochemical Transformations in Shock Waves [in Russian], RIO IKhF, Chernogolovka (1978).
M. Figner, E. Li, F. Helm, B. Heiss, et al., “Effect of elemental composition on the detonation properties of explosives,” in Detonation and Explosives [Russian translation], A. A. Borisov (ed.), Mir, Moscow (1981).
N. G. Grigoryan (ed.), Concise Handbook on Blasthole Springing [in Russian], Nedra, Moscow (1970).
V. G. Khotin, A. I. Kozlov, A. V. Akhachinskii, et al., “Effect of metallic and nonmetallic inclusions on the detonation parameters of PETN,” in: Chemical Physics of Condensed Systems of Explosives [in Russian], Vol. 104, Izd. MKhTI (Moscow Institute of Chemical Engineering) im. D. I. Mendeleev AN SSSR (1979).
V. K. Bobolev, “Limiting parameters of charges of chemically homogeneous explosives,” Dokl. Akad. Nauk SSSR, {vn57}, {snNo. 8} ({dy1947}).
V. A. Virchenko, D. A. Slutskii, and A. P. Egorov, “Calculation of the detonation parameters of explosives by the thermodynamic method,” in: Detonation [in Russian], RIO IKhF, Chernogolovka (1992).
A. K. Parfenov, I. M. Voskoboinikov, and A. Ya. Apin, “Detonation of coarse-grained explosives,” in: Detonation of Explosives and Safety of Blasting Operations. Blasting. Symposium No. 63/20 [in Russian], Nedra, Moscow (1967).
L. I. Al'bov and V. A. Vasil'ev, “Experimental study of the structure of the detonation wave in certain individual and mixed explosives,” in: Aeromechanics and Control Processes [in Russian], RIO MFTI, Dolgoprudnyi (1974).
B. N. Kondrikov and V. N. Shapoval, “Methods of calculating detonation velocity in CHNO explosives,” in: Chemical Physics of Condensed Systems of Explosives [in Russian], Vol. 104, Izd. MKhTI (Moscow Institute of Chemical Engineering) im. D. I. Mendeleev (1979).
A. Bailey, J. M. Bellerby, and S. A. Kinloch, “The identification of bonding agents for TATB/HTPB polymerbonded explosives.” Energetic Materials,339, No. 1654 (1992).
M. J. Kamlet and C. Dickinson, “Chemistry of detonation. 3. Evaluation of the simplified calculation method for Chapman-Jouguet detonation pressures on the basis of available experimental information,” J. Chem. Phys.,48, No. 1 (1968).
A. V. Utkin and G. I. Kanel', “Study of the decomposition of trotyl and desensitized hexogen in shock and detonation waves,” in: Chemical Physics of Combustion and Explosion. Detonation and Shock Waves [in Russian], RIO IKhF, Chernogolovka, Tashkent (1986).
V. S. Ilyukhin, P. F. Pokhil, O. K. Rozanov, and N. S. Shvedova, “Measurement of the Hugoniot curves of cast trotyl, crystalline hexogen, and nitromethane,” Dokl. Akad. Nauk SSSR,131, No. 4 (1960).
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Mining Institute, Siberian Branch of the Russian Academy of Sciences. Translated from Fiziko-Tekhnicheskie Problemy Razrabotki Poleznykh Iskopaemykh, No. 3, pp. 52–65, May–June, 1998.
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Muchnik, S.V. Principles of the turbo-explosion of explosive charges part 2: Calculation of the thermal effect of detonation. J Min Sci 34, 230–241 (1998). https://doi.org/10.1007/BF02803460
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DOI: https://doi.org/10.1007/BF02803460