Abstract
The phase composition of the binary phosphorus-molybdenum system with a Mo/P ratio of 3-24.5 and its catalytic properties in the reaction of oxidative ammonolysis of methylpyrazine are studied. X-ray amorphous phases of molybdenyl phosphate and phosphorus modified molybdenum trioxide are active in the formation of pyrazinonitrilee.
Similar content being viewed by others
References
FRG Patent 3 107 756, 1982.
US Patent 4931 561, 1990.
JPN Patent 6431 769, 1989.
Forni, L.,Appl. Catal., 1986, vol. 20, nos. 1–2, p. 219.
Forni, L., Oliva, C., and Rebuschini, C.,J. Chem. Soc., Faraday Trans. I, 1988, vol. 84, no. 7, p. 2397.
Kagarlitskii, A.D., Krichevskii, L.A., and Suvorov, B.V.,Khim.-Farm. Zh., 1993, no. 3, p. 45.
Pope, M.T.,Heteropoly and Isopoly Oxometalates, Berlin: Springer, 1983.
Kierkegaard, P.,Arkiv Kemi, 1962, vol. 19, no. 1, p. 51.
Popova, G.Ya. and Andrushkevich, T.V.,Kinet. Katal., 1994, vol. 35, no. 1,p. 135.
Bondareva, V.M., Andrushkevich, T.V., Detusheva, L.G., and Litvak, G.S.,Catal. Lett., 1996, vol. 42, p. 113.
Gadzhiev, K.N., Aliev, E.A., and Khanmamedova, A.K.,Tez. dokl. V konferentsii po okislitel’nomu geterogennomu katalizu (Proc. V Conf. on Oxidative Heterogeneous Catalysis), Baku, 1981, pt. 2, p. 58.
Ai, M. and Suzuki, S.,J. Catal., 1973, vol. 30, no. 3, p. 362.
Ai, M.,Kogyo Kagaku Zasshi, 1971, vol. 74, no. 1, p. 183.
Ai, M. and Ishihara, M.,Kogyo Kagaku Zasshi, 1970, vol. 73, no. 12, p. 2152.
Bondareva, V.M., Andrushkevich, T.V., and Plyasova, L.M.,React. Kinet. Catal. Lett., 1988, vol. 63, no. 1, p. 201.
Solov’eva, L.P., Tsybulya, S.V., and Zabolotnyi, VA.,POLIKRISTALL—sistema programm dlya strukturnykh raschetov (POLIKRISTALL: A Program Package of Structure Calculations), Novosibirsk: Institute of Catalysis, 1988.
Malakhov, V.V., Vlasov, A.A., Boldyreva, N.N., and Dovlitova, L.S.,Zavod. Lab., 1996, no. 2, p. 1.
Malakhov, V.V.,Zh. Anal. Khim., 1989, vol. 44, no. 7, p. 1177.
Maksimovskaya, R.I. and Bondareva, V.M.,Zh. Neorg. Khim., 1994, vol. 39, no. 8, p. 1298.
Bondareva, V.M., Andrushkevich, T.V., and Zenkovets, G.A.,Kinet. Katal., 1997, vol. 38, no. 5, p. 720.
Lepilina, R.G. and Smirnova, N.M.,Termogrammy neorganicheskikh fosfatnykh soedinenii (Thermograms of Inorganic Phospate Compounds), Leningrad: Nauka, 1984.
Chuvaev, V.R., Mailieva, G.K., Popov, K.N., and Spitsyn, V.I.,Dokl. Akad. Nauk SSSR, 1979, vol. 247, no. 5, p. 1165.
X-ray Powder Data File ASTM, 5-0508, Philadelphia, 1964.
Yurchenko, E.N., Kustova, G.N., and Batsanov, S.S.,Kolebatel’nye spektry neorganicheskikh soedinenii (Vibrational Spectra of Inorganic Compounds), Novosibirsk: Nauka, 1981, p. 82.
Nakamoto, K.,Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1997.
Bekbutov, A.B., Il’yasova, A.K., Geskina, R.A., and Shalamov, A.E.,Izv. Akad. Nauk KazSSR, Ser. Khim., 1968, no. 2, p. 1.
Karyakin, Yu.V. and Angelov, N.N.,Chistye khimicheskie veshchestva (Pure Chemicals), Moscow: Nauka, 1974.
Bondareva, V.M., Andrushkevich, T.V., Maksimovskaya, R.I.,et al., Kinet. Katal., 1994, vol. 35, no. 1, p. 129.
Maksimovskaya, R.I., Bondareva, V.M., and Litvak, G.S.,Zh. Neorg. Khim., 1996, vol. 41, no. 7, p. 1173.
Maksimovskaya, R.I.,2nd Int. Memorial G.K. Boreskov Conf., Novosibirsk, 1997, pt. II, p. 105.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bondareva, V.M., Andrushkevich, T.V., Chumachenko, N.N. et al. Oxidative ammonolysis of methylpyrazine over binary catalytic systems: III. Phosphorus-molybdenum system: Catalytic properties and the active component. Kinet Catal 41, 222–230 (2000). https://doi.org/10.1007/BF02771424
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02771424