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Journal of Structural Chemistry

, Volume 38, Issue 1, pp 83–88 | Cite as

Crystal structure of K4MnMo4O15 — A parent compound of a new isostructural series of complex oxides K4M2+Mo4O15 (M2+ = Mn, Mg, Co, Cd)

  • S. F. Solodovnikov
  • E. S. Zolotova
  • Z. A. Solodovnikova
Article

Abstract

The structure of K4MnMo4O15 was solved from single-crystal X-ray diffraction data (a = 10372, c = 8.160 Å, Z = 2, space group P-3, 2152 reflections, R = 0.039). The structure is of new, glaserite-like, type. A characteristic and original feature of the structure is a Mn(II)O6 octahedron with six MoO4 tetrahedra attached to it by their vertices; the octahedron is linked with a MoO6 octahedron by a common face. The MoO4 tetrahedra bridge the octahedral dimers with each other, forming lacy layers with potassium atoms lying between the layers. K4M2+Mo4O15 (M2+= Mg, Co, Cd) phases, which have similar structures, have been synthesized and characterized.

Keywords

CaMoO4 Potassium Atom Equivalent Isotropic Thermal Parameter Glaserite Isostructural Series 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • S. F. Solodovnikov
    • 1
  • E. S. Zolotova
    • 1
  • Z. A. Solodovnikova
    • 1
  1. 1.Institute of Inorganic Chemistry, Siberian BranchRussian Academy of SciencesRussia

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