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Crystal structure of K4MnMo4O15 — A parent compound of a new isostructural series of complex oxides K4M2+Mo4O15 (M2+ = Mn, Mg, Co, Cd)

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Abstract

The structure of K4MnMo4O15 was solved from single-crystal X-ray diffraction data (a = 10372, c = 8.160 Å, Z = 2, space group P-3, 2152 reflections, R = 0.039). The structure is of new, glaserite-like, type. A characteristic and original feature of the structure is a Mn(II)O6 octahedron with six MoO4 tetrahedra attached to it by their vertices; the octahedron is linked with a MoO6 octahedron by a common face. The MoO4 tetrahedra bridge the octahedral dimers with each other, forming lacy layers with potassium atoms lying between the layers. K4M2+Mo4O15 (M2+= Mg, Co, Cd) phases, which have similar structures, have been synthesized and characterized.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    S. F. Solodovnikov, E. S. Zolotova & Z. A. Solodovnikova

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  1. S. F. Solodovnikov
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  2. E. S. Zolotova
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  3. Z. A. Solodovnikova
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Translated from Zhumal Strukturnoi Khimii, Vol. 38, No. 1, pp. 104–110, January–February, 1997.

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Solodovnikov, S.F., Zolotova, E.S. & Solodovnikova, Z.A. Crystal structure of K4MnMo4O15 — A parent compound of a new isostructural series of complex oxides K4M2+Mo4O15 (M2+ = Mn, Mg, Co, Cd). J Struct Chem 38, 83–88 (1997). https://doi.org/10.1007/BF02768811

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