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Theoretical and Experimental Chemistry

, Volume 33, Issue 2, pp 57–60 | Cite as

Consideration of spin-orbital coupling in olefin ozonolysis

  • B. F. Minaev
  • E. M. Kozlo
Article

Abstract

Possible S-T crossings along the olefin ozonolysis pathway were examined. Spin-orbital coupling inducing S-T transitions in the Criegee intermediate near the activation barrier were explained. The role of states with different symmetry and orbital characteristics (σσ and σπ) participating in S-T transitions during a chemical transformation was noted.

Keywords

Potential Energy Surface Ozonolysis Atomic Orbital Configurational Interaction Orbital Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • B. F. Minaev
  • E. M. Kozlo

There are no affiliations available

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